We report accelerated rates of oxygen-atom transfer from a polyoxovanadate-alkoxide cluster following functionalization with a 4-butylcalix[4]arene ligand. Incorporation of this electron withdrawing ligand modifies the electronics of the metal oxide core, favoring a mechanism in which the rate of oxygen-atom transfer is limited by outer-sphere electron transfer.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1039/d2cc01228f | DOI Listing |
Publication Analysis
Top Keywords
oxygen-atom transfer
12
mechanistic insight
4
insight rapid
4
rapid oxygen-atom
4
transfer
4
transfer calix-functionalized
4
calix-functionalized polyoxovanadate
4
polyoxovanadate report
4
report accelerated
4
accelerated rates
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!