AI Article Synopsis
- The study aimed to explore how β-cyclodextrin interacts with water, focusing on adsorption characteristics like capacity, rate, and heat while using various analytical methods.
- Results revealed that the adsorption of water is exothermic and influenced by structural effects, indicating a complex interaction beyond traditional physical adsorption.
- Water adsorbs to β-cyclodextrin more easily than it desorbs, with an average intermolecular interaction strength of 67.5 kJ/mol confirmed through differential scanning calorimetry (DSC).
Article Abstract
This study focused on demonstrating the intermolecular interactions between β-cyclodextrin and water, with the aim to better understand the transfer of small molecules to β-cyclodextrin. The intermolecular interaction strength between β-cyclodextrin and water was analyzed using different methods such as the dynamic adsorption of water, the TG-DSC of β-cyclodextrin and molecular modeling employing MM2 force field calculations. The experiments for the adsorption of water on β-cyclodextrin was aimed to systematically investigate the adsorption characteristics, such as adsorption capacity, adsorption rate, adsorption heat and activation energy, influenced by the adsorption temperature and vapor pressure of water. The results indicated that the water adsorption on β-cyclodextrin is an exothermic process. The hysteresis loop type in the adsorption isotherms at multiple temperatures indicated that water adsorption is not purely a traditional physical adsorption due to the existence of structure effects such as the cavity effect and hydrogen bonding. The activation energy during water adsorption was 7.4 kJ mol. However, the activation energy during water desorption was in the range of 35-45 kJ mol, which decreased with an increase in the amount of water adsorbed. This indicated that water adsorption is much easier than water desorption from β-cyclodextrin and that water desorption is more difficult with a small amount of adsorbed water compared with a large amount of adsorbed water. Subsequently, the obtained average intermolecular interaction strength between β-cyclodextrin and water under the experimental conditions was 67.5 kJ mol (water), which was verified by DSC.
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|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9037024 | PMC |
| http://dx.doi.org/10.1039/d1ra03960a | DOI Listing |
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