Two new hybrid organic-inorganic compounds, which incorporate 3,3'-diammoniumdiphenylsulfone or 4,4'-diammoniumdiphenylsulfone cations and sulfate anions, were synthesized and analyzed in detail. The crystal structures of both systems were established using single-crystal X-ray diffraction analysis. Crystallographic study revealed that the crystals of both investigated compounds were constructed of repeatedly occurring organic and inorganic layers and allowed the description of their structural features. Dense networks of N-H⋯O hydrogen bonds were found in both crystals. In addition, S-O⋯π contacts and weak C-H⋯O hydrogen bonds were identified in each analyzed crystal network. All intermolecular interactions were quantitatively described by Hirshfeld surface analysis. Furthermore, a C NMR study was conducted for the grown crystals. The functional groups present in the titular compounds were also the subjects of IR and Raman spectral studies. Finally, TGA/DSC and UV-vis absorption measurements were performed and allowed the thermal and optical characterization of the titular materials.
Download full-text PDF |
Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9037390 | PMC |
| http://dx.doi.org/10.1039/d1ra03696c | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Synthesizing hybrid copper phosphate (Cu(PO)) nanoflowers using Cu and shed snakeskin: antioxidant, antibacterial, anticancer, guaiacol, anionic, and cationic dye degradation properties.
J Biol Eng
January 2025
Department of Aquatic Animals and Diseases, Faculty of Veterinary Medicine, Erciyes University, Kayseri, Türkiye.
Background: Synthesis of organic@inorganic hNFs is achieved by the coordination of organic compounds containing amine, amide, and diol groups with bivalent metals. The use of bio-extracts containing these functional groups instead of expensive organic inputs such as DNA, enzymes, and protein creates advantages in terms of cost and applicability. In this study, the application potentials (antioxidant, antibacterial, anticancer, guaiacol, anionic, and cationic dye degradation) of hybrid (organic@inorganic) nanoflowers (hNFs) synthesized with Cu and snakeskin (SSS) were proposed.
View Article and Find Full Text PDFEffect of Halogenation on the Optical, Electrical, and Thermal Properties of the Model Compound [Me(i-Pr)N][SnBr].
Inorg Chem
January 2025
School of Chemistry and Chemical Engineering, Nanchang University, Nanchang 330031, P. R. China.
Organic-inorganic hybrid lead halides have been extensively studied due to their outstanding physical properties and diverse compositional elements. However, environmentally benign tin-based hybrids with remarkable flexibility in bandgap engineering have been less investigated. Herein, we report the successful design and synthesis of three tin-based organic-inorganic hybrid compounds through precise molecular modification: [Me(i-Pr)N][SnBr] (), [MeCHCl(i-Pr)N][SnBr] (), and [MeCHBr(i-Pr-Br)N][SnBr] ().
View Article and Find Full Text PDFCationic Modification in Hybrid Iodates: A Pathway to Superior Performance.
Inorg Chem
January 2025
Key Laboratory of Functional Molecular Solids, Ministry of Education, College of Chemistry and Materials Science, Anhui Normal University, Wuhu, Anhui 241002, P. R. China.
The utilization of nonlinear optical (NLO) crystals plays a crucial role in the contemporary laser industry, and the advancement of novel NLO-active units is essential for the exploration of NLO materials. Two novel organic-inorganic hybrid iodates, designated as (CNH)MoO(IO)·3HO () and (CNIH)MoO(IO)·4HO () were synthesized via mild hydrothermal methods, exhibiting band gaps of 3.75 and 3.
View Article and Find Full Text PDFUltra-Flexible High-Linearity Silicon Nanomembrane Synaptic Transistor Array.
Adv Mater
January 2025
School of Electronic and Computer Engineering, Peking University, Shenzhen, 518055, China.
The increasing demand for mobile artificial intelligence applications has elevated edge computing to a prominent research area. Silicon materials, renowned for their excellent electrical properties, are extensively utilized in traditional electronic devices. However, the development of silicon materials for flexible neuromorphic computing devices encounters great challenges.
View Article and Find Full Text PDFRecent Advances in Enantiorecognition and Enantioseparation Techniques of Chiral Molecules in the Pharmaceutical Field.
Biomed Chromatogr
February 2025
Department of Pharmaceutical Chemistry and Analysis, ISF College of Pharmacy, Moga, Punjab, India.
Enantioseparation and enantiorecognition are crucial in the pharmaceutical analysis of chiral substances, impacting safety, efficacy, and regulatory compliance. Enantioseparation refers to the process of separating enantiomers from a mixture, typically achieved through chromatography techniques like HPLC and SFC. In contrast, enantiorecognition involves the identification of enantiomers based on their interaction with a chiral selector without the need for separation.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!