Enhanced charge separation in LaNiO nanoplates by coupled piezocatalysis and photocatalysis for efficient H evolution.

Photocatalytic hydrogen evolution is one promising method for solar energy conversion, but the rapid charge recombination limits its efficiency. To this end, in this work, grain size, and hence the charge carrier migration path, is reduced by lowering the synthesis temperature of two-dimensional visible light-responsive LaNiO perovskite. Interestingly, the hydrogen yield for the piezoelectric response of LaNiO under only 40 kHz ultrasonic vibration is as high as 680 μmol h g, which is 80 times that under only 600 mW cm visible light irradiation. More surprisingly, the hydrogen production rate under both light illumination and ultrasonic vibration is 129 times higher than under visible light irradiation alone. Clearly, a synergistic effect exists between piezocatalysis and photocatalysis. The hydrogen production activity of the samples with water splitting can reach 1097 μmol h g without any sacrificial reagent or co-catalyst, when the light intensity reaches about 1000 mW cm, which is a much higher hydrogen evolution rate by piezo-photocatalysis than is achieved by either piezocatalysis or photocatalysis individually. Further analysis indicates that the internal electric field generated by deformation of the LaNiO edge under piezoelectric action facilitates the directional separation and migration of photogenerated charges, which in turn significantly enhances the efficiency of use of photogenerated charges for hydrogen production. The investigation here provides a novel approach to design a new reaction system for hydrogen production by coupling multiple external physical fields.