Herein, we report a bacteria-based strategy as an efficient, reasonable, benign, and promising methodology for remediating heavy metals fed waterbodies. The contemporary study deals with isolating, screening, and characterizing heavy metal resistive bacteria from metal-rich sites. The transcriptome analysis reveals the identity of the isolated species as Bacillus pumilus and Bacillus cereus. Batch studies put forth the bioremoval results in designed conditions of different pH, concentration, dose, and time. The mechanistic actions are drawn using complementary techniques such as Scanning Electron Microscopy (SEM) and Fourier Transform Infrared Spectroscopy (FTIR). The theory of surface adsorption of lead (Pb(II)) and nickel (Ni(II)) is further fostered by the application of adsorption isotherms. The conducted studies establish the bacterial morphological stratagems and multifarious biochemical approaches for countering metallic ions of Pb(II) and Ni(II). The exhibition of significant removal results by the isolated bacterial strains in simulated water samples with remarkable proliferation rates has opened up its favorability for industrial platforms.
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http://dx.doi.org/10.1016/j.envres.2022.113337 | DOI Listing |
Bull Environ Contam Toxicol
December 2024
Department of Chemistry, Faculty of Science, Ondokuz Mayıs University, Kurupelit, Samsun, 55139, Türkiye.
Fast-paced global industrialization due to population growth poses negative water implications, such as pollution by heavy metals. Phytoremediation is deemed as an efficient and environmentally friendly alternative which utilizes different types of hyperaccumulator plants known as macrophytes for the removal of heavy metal pollutants from contaminated water. In this study, the removal of Cu(II), Ni(II), Pb(II), and Cd(II) heavy metal ions contaminated water was studied by using an aquatic plant, Persicaria amphibia (L.
View Article and Find Full Text PDFFood Chem
December 2024
Department of Chemistry, Faculty of Sciences, Erciyes University, 38039 Kayseri, Türkiye; Technology Research & Application Center (ERU-TAUM), Erciyes University, 38039 Kayseri, Türkiye; Turkish Academy of Sciences (TUBA), Çankaya, Ankara, Türkiye. Electronic address:
A novel dispersive solid phase microextraction (dSP-ME) technique using activated carbon cloth (ACC) and layered double hydroxide (LDH) has been developed for enriching and extracting Pb(II) and Ni(II). The ACC@MnCoAl-LDH nanosorbent, has proven with high surface area, superior extraction dynamics and efficiency, compared to traditional sorbents. Structural features of the new ACC@MnCoAl-LDH sorbent were also characterized.
View Article and Find Full Text PDFSci Rep
November 2024
Department of Inorganic Chemistry, Shahid Beheshti University, Tehran, 19839 69411, Iran.
Five metal dithiocarbamate complexes [M(PTHIQDTC)] [where PTHIQDTC is (S)-1-phenyl-1,2,3,4-tetrahydroisoquinoline dithiocarbamate anion and M is Ni(II) (1), Sn(II) (2), Hg(II) (3), Pb(II) (4) and Zn(II) (5)] were synthesized from the reaction of MX (X is Cl for 1-3 and OAc for 4-5) with ligand of triethylammonium (S)-1-phenyl-1,2,3,4-tetrahydroisoquinoline dithiocarbamate [EtNH][PTHIQDTC] in methanolic solution at room temperature. The five complexes were characterized by IR, H andC NMR, mass spectrometry, elemental analysis and TGA analysis. Recrystallization of [Zn(PTHIQDTC)] (5) in dimethylsulfoxide (DMSO) converts 5 to [Zn(PTHIQDTC)(DMSO)] (6).
View Article and Find Full Text PDFEnviron Sci Process Impacts
December 2024
School of Chemistry and Chemical Engineering, University of Surrey, Guildford, Surrey GU2 7XH, UK.
Sci Total Environ
December 2024
College of Life Science, College of Marine Science and Engineering, Nanjing Normal University, Nanjing 210023, China. Electronic address:
The study of the competitive and selective immobilization properties and mechanisms of pollutants immobilized by metastable biogenic monohydrocalcite is of great importance for the assessment of the eco-environmental effects and applications of hydrated calcite at the Earth's poles. Microbial culture technology was used to induce the synthesis of biogenic monohydrocalcite (BMHC), and mineral characterization, batch adsorption experiments and chemical analyses were further used to investigate the sequestration characteristics, action mechanism, and environmental effects of BMHC on Pb(II)-Ni(II)-Zn(II)-methylene blue (MB) compound pollution. The results show that BMHC is an organic-inorganic mineral composite (about 3.
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