Metastability is a ubiquitous phenomenon in nature, which interests several fields of natural sciences. Since metastability is a genuine non-equilibrium phenomenon, its description in the framework of thermodynamics and statistical mechanics has progressed slowly for a long time. Since the publication of the first seminal paper in which the metastable behavior of the mean field Curie-Weiss model was approached by means of stochastic techniques, this topic has been largely studied by the scientific community. Several papers and books have been published in which many different spin models were studied and different approaches were developed. In this review, we focus on the comparison between the metastable behavior of synchronous and asynchronous dynamics, namely, stochastic processes in discrete time in which, at each time, either all the spins or one single spin is updated. In particular, we discuss how two different stochastic implementations of the very same Hamiltonian give rise to different metastable behaviors.
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http://dx.doi.org/10.3390/e24040450 | DOI Listing |
Proc SIGCHI Conf Hum Factor Comput Syst
May 2024
Remote sighted assistance (RSA) offers prosthetic support to people with visual impairments (PVI) through image- or video-based conversations with remote sighted assistants. While useful, RSA services introduce privacy concerns, as PVI may reveal private visual content inadvertently. Solutions have emerged to address these concerns on image-based asynchronous RSA, but exploration into solutions for video-based synchronous RSA remains limited.
View Article and Find Full Text PDFClin Teach
February 2025
Department of Pharmacology, Faculty of Medicine, Chulalongkorn University, Bangkok, Thailand.
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Approach: Two classes of second-year medical students were compared.
JACC Adv
December 2024
Yale School of Medicine, New Haven, Connecticut, USA.
Background: Cardiovascular disease (CVD) is the leading cause of death in low- and middle-income countries such as Haiti. Our team has demonstrated in a pilot study the implementation of a virtual cardiology curriculum to address the deficit of cardiology education in Haiti among medicine residents.
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Ophthalmologie
January 2025
Medizinische Hochschule Hannover, Carl-Neuberg-Str. 1, 30625, Hannover, Deutschland.
Background: Challenges in practice-oriented teaching at university clinics are increasing. A lack of resources contrasts a growing number of students. Digital lectures, seminars, and blended-learning concepts enable resource-efficient and effective teaching in ophthalmology.
View Article and Find Full Text PDFChemphyschem
January 2025
University of Namur, Department of Chemistry, Rue de Bruxelles, 61, 5000, Namur, BELGIUM.
The [4+2] Diels-Alder cycloaddition reaction between 2,5-DMF (1) and ethylene derivatives (2a-h) activated by electron-withdrawing groups has been studied at the density functional theory levels using a panoply of tools to unravel the reaction mechanisms. From the analysis of the reactivity indices, 2a-h behave as electrophiles while 1 as nucleophile, and the activation of the double bond of ethylene increases its electrophilicity, which is accompanied by an enhancement of the polarity of the reaction. The activation Gibbs free energy decreases linearly as a function of this increase of polarity, as estimated by the electrophilicity difference between the reactants.
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