A series of -octadecane/mesoporous silica (C/MS) shape-stabilized phase change materials (SSPCMs) with varying C content were prepared, and the effects of adsorbed C distributed within porous MS on the thermal properties were analyzed. As characterized, C was first infiltrated into the mesoporous space, resulting in a SSPCM with a maximum of ∼52 wt % C. Additional adsorption of C occurred on the external surface of MS. Consequently, the optimum 70 wt % C SSPCM had no C leakage and exhibited a heat storage capacity of 135.6 J/g and crystallinity of 83.5%, which were much larger than those of 52 wt % C SSPCM (60.2 J/g and 68.2%, respectively). The prepared C/MS SSPCMs showed excellent thermal stability and thermal reliability up to 1000 accelerated thermal cycle tests. Moreover, the C/MS SSPCM incorporated in gypsum effectively reduced the temperature changes compared with the original gypsum, suggesting the promising application of the prepared C/MS SSPCM for energy-saving building applications.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9016875 | PMC |
| http://dx.doi.org/10.1021/acsomega.2c00623 | DOI Listing |
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