The distribution of mercury species was studied in all aquatic ecosystem components (i.e., water, sediment, emergent aquatic plants, invertebrates and omnivorous and piscivorous fish) of the Záskalská water reservoir (Central Bohemia, Czech Republic) which is in the vicinity of an abandoned cinnabar mine. The results indicate that the transport of mercury from the cinnabar mine is the major source of mercury in the Záskalská reservoir. The legal maximum limit (0.07 μg/L) for total mercury concentration in water samples was exceeded only during rainy periods. The total mercury concentration in the surface sediments was in the range from 0.22 to 9.19 mg/kg in dry matter (up to 0.2% CHHg) and was sample site-specific. The dominant form of mercury in sediments was mercury sulphide (22.9-79.2%). The emergent macrophytes accumulated mercury primarily by the roots from sediments, and no significant translocation of mercury to leaves was observed. The legal maximum limit for mercury content in fish muscle (0.5 mg/kg in the fresh matter) was exceeded up to 4.48 times for piscivorous fish. Hazard index values indicate a health risk concern for children and for people consuming more than 100 g of fish muscle per day. Our results emphasise the need to implement legal restrictions on the consumption of piscivorous fish caught in ecosystems downstream of abandoned cinnabar mines.
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http://dx.doi.org/10.1007/s11356-022-20159-4 | DOI Listing |
Environ Monit Assess
October 2024
Universidad Autónoma de Nuevo León, UANL, Facultad de Ciencias Químicas, Cd. Universitaria, Ave. Universidad S/N, 66455, San Nicolás de Los Garza, NL, México.
Environ Res
September 2024
Department of Earth Sciences, University of Florence, Via G. La Pira 4, Florence, 50121, Italy.
Mining operations generate sediment erosion rates above those of natural landscapes, causing persistent contamination of floodplains. Riparian vegetation in mine-impacted river catchments plays a key role in the storage/remobilization of metal contaminants. Mercury (Hg) pollution from mining is a global environmental challenge.
View Article and Find Full Text PDFEnviron Sci Pollut Res Int
May 2023
Dipartimento di Matematica e Geoscienze, Università di Trieste, Via Weiss 2, 34128, Trieste, Italy.
Environ Sci Pollut Res Int
August 2022
Department of Zoology, Fisheries, Hydrobiology and Apiculture, Mendel University in Brno, Zemedelska 1, 61300, Brno, Czech Republic.
The distribution of mercury species was studied in all aquatic ecosystem components (i.e., water, sediment, emergent aquatic plants, invertebrates and omnivorous and piscivorous fish) of the Záskalská water reservoir (Central Bohemia, Czech Republic) which is in the vicinity of an abandoned cinnabar mine.
View Article and Find Full Text PDFEnviron Pollut
August 2021
Department of Zoology, Fisheries, Hydrobiology and Apiculture, Mendel University in Brno, Zemedelska 1, CZ-61300, Brno, Czech Republic.
Knowledge of the concentration of the bioavailable forms of mercury in the soil is necessary, especially, if these soils contain above-limit total mercury concentrations. The bioavailability of mercury in soil samples collected from the vicinity of abandoned cinnabar mines was evaluated using diffusive gradients in the thin films technique (DGT) and mercury phytoaccumulation by vegetables (lettuce, spinach, radish, beetroot, carrot, and green peas). Mercury was accumulated primarily in roots of vegetables.
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