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Regulation of Multistep Spin Crossover Across Multiple Stimuli in a 2-D Framework Material. | LitMetric

AI Article Synopsis

  • The study examines how different external factors affect the structural properties and spin-crossover behaviors in a two-dimensional material called [Fe(cintrz)Pd(CN)]·guest, focusing on various guest molecules (3HO, 2HO, and Ø).
  • The framework shows a balance between ferro- and antiferro-elastic interactions, which can be adjusted by changing the type of guest molecules present.
  • The research reveals that elastic strain stabilizes a mixed spin state at low temperatures, and this stability can be disrupted by removing guest molecules, using light to induce spin transitions, or applying external pressure.

Article Abstract

We investigate the effects of a broad array of external stimuli on the structural, spin-crossover (SCO) properties and nature of the elastic interaction within the two-dimensional Hofmann framework material [Fe(cintrz)Pd(CN)]·guest (cintrz = -cinnamalidene 4-amino-1,2,4-triazole; ·guest; guest = 3HO, 2HO, and Ø). This framework exhibits a delicate balance between ferro- and antiferro-elastic interaction characters; we show that manipulation of the pore contents across guests = 3HO, 2HO, and Ø can be exploited to regulate this balance. In ·3HO, the dominant antiferroelastic interaction character between neighboring Fe sites sees the low-temperature persistence of the mixed spin-state species {HS-LS} for {Fe1-Fe2} (HS = high spin, LS = low spin). Elastic interaction strain is responsible for stabilizing the {HS-LS} state and can be overcome by three mechanisms: (1) partial (2HO) or complete (Ø) guest removal, (2) irradiation via the reverse light-induced excited spin-state trapping (LIESST) effect (λ = 830 nm), and (3) the application of external hydrostatic pressure. Combining experimental data with elastic models presents a clear interpretation that while guest molecules cause a negative chemical pressure, they also have consequences for the elastic interactions between metals beyond the simple chemical pressure picture typically proposed.

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Source
http://dx.doi.org/10.1021/acs.inorgchem.2c00530DOI Listing

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