Treatment of a κ-P-monodentate bicyclic diphosphane iridium(III) complex with a labile gold(I) precursor afforded an unusual Ir/Au complex in which the P-P single bond has been cleaved. This reaction was cleanly reversed upon addition of tertiary phosphine. Carbon-carbon bond activation, across neighbouring PCN rings of the coordinated bicyclic diphosphane, occurred upon thermolysis of the Ir/Au complex.
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| http://dx.doi.org/10.1039/d2cc00706a | DOI Listing |
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