In this study, a simple method without any additional chemical modification is proposed to fabricate underoil superhydrophobic surfaces with micro- and nano-hierarchical structures using a nanosecond laser system. The fabricated surfaces exhibited extreme superhydrophobicity and underoil superhydrophobicity with high contact angles of 153.8 ± 1.5° and 161.3 ± 1.1°, respectively. The results show that even after 20 abrasion cycles, the fabricated surfaces retained water repellency and self-cleaning performance under oil, while the superhydrophobicity in air was not resistant to wear. In addition, the fabricated brass meshes can also be used to separate oil in an oil-water mixture based on the prewetting induced underoil superhydrophobicity after being damaged. The separation efficiency was as high as 97.8%, which made them more appropriate for the oil-water separation than those based on superhydrophobicity. The proposed fabrication method is suitable for large-scale and mass production and provides a new avenue and possibility for further development of robust functional interface materials.
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http://dx.doi.org/10.1039/d1ra06422c | DOI Listing |
Nano Lett
October 2024
Innovation Center for Textile Science and Technology, College of Textiles, Donghua University, Shanghai 200051, China.
Molecules
July 2024
School of Material and Chemical Engineering, Hunan City University, Yiyang 413000, China.
The development of superlyophobic materials in liquid systems, enabling synchronous oil/water separation and dye removal from water, is highly desirable. In this study, we employed a novel superwetting array-like BiOBr nanosheets anchored on waste rock wool (RW) fibers through a simple neutralization alcoholysis method. The resulting BiOBr/RW fibers exhibited superoleophilic and superhydrophilic properties in air but demonstrated underwater superoleophobic and underoil superhydrophobic characteristics.
View Article and Find Full Text PDFLangmuir
May 2024
College of Chemistry and Chemical Engineering, Southwest Petroleum University, Chengdu 610500, P. R. China.
To achieve the green, sustainable, and controllable recovery of oil-water resources and to address the limited functionality of single superwet materials in oil-water separation, this study reports a multifunctional oil-water separation strategy by compositing the underwater superoleophobic and underoil superhydrophobic materials (HS). The underwater superoleophobic quartz sands with an oil contact angle of 152.68° were prepared by adjusting the particle size.
View Article and Find Full Text PDFPolymers (Basel)
March 2024
Graduate Institute of Applied Science and Technology, Advanced Membrane Materials Research Center, National Taiwan University of Science and Technology, Taipei 106, Taiwan.
Oil/water separation processes have garnered significant global attention due to the quick growth in industrial development, recurring chemical leakages, and oil spills. Hence, there is a significant demand for the development of inexpensive superwetting materials in an eco-friendly manner to separate oil/water mixtures and emulsions. In this study, a superwetting melamine sponge (SMS) with switchable wettabilities was prepared by modifying melamine sponge (MS) with sodium dodecanoate.
View Article and Find Full Text PDFJ Hazard Mater
March 2024
State Key Laboratory of Advanced Technology for Materials Synthesis and Processing & Shenzhen Research Institute & Laoshan Laboratory, Wuhan University of Technology, 122 Luoshi Road, Wuhan 430070, China. Electronic address:
Separating water-in-oil emulsions is important in terms of environmental protection and resource recovery. To address the challenges posed by the water-oil interface, superwetting materials have been designed to accomplish separation through filtration and adsorption. Superhydrophobic membranes prevent the permeation of water droplets owing to extreme repellence and their size-sieving abilities.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!