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High-Performance Membranes Based on Spherical-Beaded Nanofibers and Nanoarchitectured Networks for Water-in-Oil Emulsion Separation.

Nano Lett

October 2024

Innovation Center for Textile Science and Technology, College of Textiles, Donghua University, Shanghai 200051, China.

Article Synopsis
  • High-performance membranes made of spherical-beaded nanofibers and nanoarchitectured networks are developed for separating water-in-oil emulsions, which are important for environmental protection.
  • These membranes are created using electrostatic spinning technology and feature small pores due to the self-assembly of charged droplets, enabling efficient phase separation.
  • The membranes show remarkable properties like superhydrophobicity (>152°), high separation efficiency (>99.2%), significant flux (5775 L m² h), and are reusable and antifouling, suggesting new possibilities for improving separation materials.
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The development of superlyophobic materials in liquid systems, enabling synchronous oil/water separation and dye removal from water, is highly desirable. In this study, we employed a novel superwetting array-like BiOBr nanosheets anchored on waste rock wool (RW) fibers through a simple neutralization alcoholysis method. The resulting BiOBr/RW fibers exhibited superoleophilic and superhydrophilic properties in air but demonstrated underwater superoleophobic and underoil superhydrophobic characteristics.

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To achieve the green, sustainable, and controllable recovery of oil-water resources and to address the limited functionality of single superwet materials in oil-water separation, this study reports a multifunctional oil-water separation strategy by compositing the underwater superoleophobic and underoil superhydrophobic materials (HS). The underwater superoleophobic quartz sands with an oil contact angle of 152.68° were prepared by adjusting the particle size.

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Oil/water separation processes have garnered significant global attention due to the quick growth in industrial development, recurring chemical leakages, and oil spills. Hence, there is a significant demand for the development of inexpensive superwetting materials in an eco-friendly manner to separate oil/water mixtures and emulsions. In this study, a superwetting melamine sponge (SMS) with switchable wettabilities was prepared by modifying melamine sponge (MS) with sodium dodecanoate.

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Effective separation of water-in-oil emulsions using an under-medium superlyophilic membrane with hierarchical pores.

J Hazard Mater

March 2024

State Key Laboratory of Advanced Technology for Materials Synthesis and Processing & Shenzhen Research Institute & Laoshan Laboratory, Wuhan University of Technology, 122 Luoshi Road, Wuhan 430070, China. Electronic address:

Separating water-in-oil emulsions is important in terms of environmental protection and resource recovery. To address the challenges posed by the water-oil interface, superwetting materials have been designed to accomplish separation through filtration and adsorption. Superhydrophobic membranes prevent the permeation of water droplets owing to extreme repellence and their size-sieving abilities.

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