An azide masked amine is used to obtain a cage of lower symmetry that possess one terpy-group in an -position. This group can coordinate to iron(ii), yielding selectively an easy to purify Fe(terpy-cage) dumbbell. The dumbbell can also be obtained in a one pot reaction, which proceeded without isolation of the -functionalized cage.
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|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC8979284 | PMC |
| http://dx.doi.org/10.1039/d1ra08994c | DOI Listing |
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