AI Article Synopsis

  • - The text discusses efforts to create effective CO adsorbents aimed at reducing carbon emissions and meeting climate change targets, focusing on silsesquioxane pillared graphene oxide.
  • - Researchers manipulated silsesquioxane loading and processing parameters to develop materials with specifically designed nanopores and surface properties for improved CO capture.
  • - Characterization techniques showed that the optimized materials achieved significant CO storage capacities of up to 1.7 mmol/g at 273 K and 1.5 mmol/g at 298 K under atmospheric pressure.

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Article Synopsis
  • - The text discusses efforts to create effective CO adsorbents aimed at reducing carbon emissions and meeting climate change targets, focusing on silsesquioxane pillared graphene oxide.
  • - Researchers manipulated silsesquioxane loading and processing parameters to develop materials with specifically designed nanopores and surface properties for improved CO capture.
  • - Characterization techniques showed that the optimized materials achieved significant CO storage capacities of up to 1.7 mmol/g at 273 K and 1.5 mmol/g at 298 K under atmospheric pressure.
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Iron-substituted cubic silsesquioxane pillared clays: Synthesis, characterization and acid catalytic activity.

J Colloid Interface Sci

January 2018

Zernike Institute for Advanced Materials, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The Netherlands. Electronic address:

Novel pillared structures were developed from the intercalation of iron-substituted cubic silsesquioxanes in a sodium and an acid-activated montmorillonite nanoclay and evaluated as acid catalysts. Octameric cubic oligosiloxanes were formed upon controlled hydrolytic polycondensation of the corresponding monomer (a diamino-alkoxysilane) and reacted with iron cations to form complexes that were intercalated within the layered nanoclay matrices. Upon calcination iron oxide nanoparticles are formed which are located on the silica cubes (pillars) and on the surfaces of the clay platelets.

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Zeolite-derived hybrid materials with adjustable organic pillars.

Chem Sci

June 2016

J. Heyrovský Institute of Physical Chemistry, Academy of Sciences of the Czech Republic , v.v.i., Dolejškova 3 , CZ-182 23 Prague 8 , Czech Republic . Email:

Porous organic-inorganic materials with tunable textural characteristics were synthesized using the top-down process by intercalating silsesquioxanes and polyhedral oligomeric siloxanes of different types between crystalline zeolite-derived layers. The influence of key parameters such as (i) linker nature (pure hydrocarbon, S-, N-containing); (ii) chain length in alkyl- and aryl bis(trialkoxysilyl) derivatives; (iii) denticity of the organic precursor molecules; (iv) nature and size of side chain in mono(trialkoxysilyl) substrates; (v) rigidity of the chain (saturated unsaturated, aliphatic aromatic); (vi) nature and size of leaving group on the structural and textural properties of formed hybrids was carefully addressed. It was established, that the optimal silsesquioxane appropriate for the formation of zeolite-derived hybrids with high textural characteristics should possess short alkyl or long aryl chains, relatively small leaving groups and denticity larger than 3.

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Fabrication of Hybrid Organic-Inorganic Materials with Tunable Porosity for Catalytic Application.

Chempluschem

March 2015

Department of Synthesis and Catalysis, J. Heyrovský Institute of Physical Chemistry, Academy of Sciences of Czech Republic v.v.i Dolejškova 3, 18223 Prague 8 (Czech Republic), Fax: (+420) 28658 2307.

Novel layered organic-inorganic materials functionalized with amino groups have been synthesized by using a two-dimensional zeolitic precursor, IPC-1P, prepared by a top-down approach from zeolite UTL. The formation of porous materials containing silsesquioxane linkers covalently bonded to zeolite layers in the interlayer space was confirmed by a variety of characterization techniques (N  sorption, XRD, TEM). The textural properties and catalytic behavior of functionalized hybrid materials synthesized by direct pillaring of IPC-1P or by grafting of (3-aminopropyl)silyl groups to the IPC-1P precursor preliminarily pillared with tetraethoxysilane (TEOS) were compared.

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An optical scattering layer, consisting of a Si3N4 nano-pillar array and a spin-coated hydrogen silsesquioxane (HSQ) planarization layer, was introduced to an organic light-emitting diode (OLED) substrate to increase the out-coupling efficiency. After plasma enhanced chemical vapor deposition (PECVD) of the Si3N4 layer, the nano-pillar array was created using nanoimprint lithography and reactive ion etching. As the Si3N4 pillar array has a refractive index of 2.

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