A Janus membrane/mesh is a type of functional membrane/mesh composed of opposing wetting properties formed into a single layer in order to achieve novel properties. Janus membranes/meshes have attracted increasing attention from materials scientists due to their promising applications in the fields of microfluid transportation, water-oil separation and cleaning energy applications. Herein, we report a simple method to fabricate a Janus mesh by combining opposite wettability functions into one copper mesh substrate. The superhydrophilicity is achieved by chemical etching and the superhydrophobicity is fabricated by hydrophobic SiO nanoparticle spraying. Due to its special composition and structure, the prepared mesh demonstrates distinct wetting properties on its two sides. Meanwhile, aqueous fluids can pass through the mesh from the hydrophobic side to the hydrophilic side spontaneously, whilst being blocked by the mesh when coming from the other direction. This unique property can realize unidirectional transportation of water fluids. The mechanism of the unique property based on Janus wettability is proposed and the stability of the prepared Janus mesh was also tested. The prepared Janus mesh can be used in the fields of microtidal energy, the chemical industry and in astronautics, demonstrating promising practical prospects.
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http://dx.doi.org/10.1039/d0ra08632k | DOI Listing |
Nanoscale Horiz
January 2025
Ministry of Education Key Laboratory for the Green Preparation and Application of Functional Materials, Hubei University, Wuhan 430062, People's Republic of China.
Coordinating the droplet capture, transport, and shedding processes during fog collection to achieve efficient fog collection is a major challenge. In this study, a copper mesh with different wettability was prepared by chemical etching and thiol modification. The Cu(OH) needle structure on the surface of the samples was characterized by FE-SEM and EDS tests, and the surface of the samples was chemically analyzed by infrared and XPS analyses.
View Article and Find Full Text PDFActa Biomater
December 2024
School of Chemistry and Pharmaceutical Engineering, Medical Science and Technology Innovation Center, Shandong First Medical University & Shandong Academy of Medical Sciences, Jinan, 250021, China. Electronic address:
Postoperative adhesion (PA) caused by the combination of proteins, inflammatory response and bacterial infection poses substantial challenges for polypropylene meshes (PPMs) based hernioplasty. Herein, inspired by the peritoneum, a Janus PPMs with side-specific functions was developed via a surface-initiated photoiniferter-mediated polymerization technology. A physical barrier composed of zwitterionic polymer brushes (PS) was firstly constructed on the one side of the PPMs, while the polymethacrylic acid (PMAA) brushes acting as the linker for bioactive nanoparticles (HAP) were precisely situated on the opposite surface subsequently.
View Article and Find Full Text PDFJ Colloid Interface Sci
November 2024
College of Materials Science and Engineering, Liaoning Technical University, Fuxin 123000, China. Electronic address:
Water splitting, as a promising clean energy source, has garnered significant attention owing to the escalating global energy crisis. However, prior research has largely focused on electrode materials rather than bubble manipulation, which plays a crucial role in the process. Although using the previously published "Releasing strategy" effectively eliminates micro-sized bubbles from the electrode material for efficient water splitting, the released tiny-sized bubbles pose challenges for controllable and pure collection.
View Article and Find Full Text PDFACS Appl Mater Interfaces
November 2024
Department of Chemical and Biological Engineering, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon 999077, Hong Kong SAR.
Water scarcity is a critical global challenge, especially in arid and semiarid regions. Fog harvesting has emerged as a promising solution; however, concerns about air pollution and bacterial growth in humid environments have raised doubts about the safety and sustainability of such systems. This study introduces a Janus mesh with asymmetric wettability on its two faces, fabricated through a simple and scalable method.
View Article and Find Full Text PDFLangmuir
May 2024
National Engineering Research Center for High Efficiency Grinding, Hunan University, Changsha, Hunan 410082, People's Republic of China.
Janus mesh with two-sided asymmetric wettability shows high potential for selective oil-water and emulsion separation. However, it remains a challenge to construct Janus mesh structures with good stability and extremely asymmetric wettability. Herein, a novel Janus mesh with asymmetric wettability was structured by two different precursors, polydimethylsiloxane/zinc oxide (PDMS/ZnO) and zinc oxide-polyacrylonitrile/,-dimethylformamide (ZnO-PAN/DMF), by electrostatic printing, including electrostatic air spraying and electrostatic spinning.
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