Carbon nanotubes (CNTs) have been considered as promising electrode materials for energy storage devices, especially flexible electronics owing to their excellent electrical, physicochemical and mechanical properties. However, the severe aggregation between CNTs significantly reduces the electrochemically active surface areas and thus degrades the electrochemical properties. In this study, we demonstrate a facile layer-by-layer strategy toward preparing a CNT/hollow carbon nanocage (HCNC) hybrid film. Through electrochemically removing the impurities in CNT films and optimizing the concentrations of HCNC, the hybrid film exhibits a high specific capacitance of 183.7 F g at 10 mV s and good cycling stability of 85% retention after 5000 cycles at 1 A g. Our study provides potential scale-up synthesis of free-standing CNT electrode materials for high-performance supercapacitors.
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http://dx.doi.org/10.1039/d0ra09710a | DOI Listing |
Colloids Surf B Biointerfaces
December 2024
The Affiliated Guangdong Second Provincial General Hospital of Jinan University, PR China. Electronic address:
Alpha-fetoprotein (AFP), serves as a reliable and vital biomarker for precise diagnosis and effective monitoring of hepatocellular carcinoma, requires precise detection. Herein, a sandwich-structured electrochemical immunosensor was crafted, employing three-dimensional layered porous carbon modified with gold nanoparticles (Au NPs) as the substrate and Au NPs/CuS as the labeling compound for accurate and sensitive detection of AFP. Due to the effective coordination between the 3D carbon network, Au NPs, and hollow CuS nanocubes, the sandwich-structured electrochemical immunosensor was able to produce three distinct response signals via various detection techniques, demonstrating a broad linear range (0.
View Article and Find Full Text PDFSmall
December 2024
School of Electrical, Computer and Energy Engineering, Arizona State University, Tempe, AZ, 85281, USA.
Electrochemical capacitors (ECs) offer superior specific capacitance for energy storage compared to traditional electrolytic capacitors but face limitations in alternating current (AC) filtering due to the need for balancing fast response and high capacitance. This study addresses these challenges by developing a freestanding nanostructured carbon electrode, derived from the rapid carbonization of bacterial cellulose (BC) embedded with zeolitic imidazolate framework 8 (ZIF-8) and in situ formed carbon nanotubes (CNTs). The electrode exhibits an exceptionally low area resistance of 9.
View Article and Find Full Text PDFAdv Sci (Weinh)
December 2024
College of Architecture & Civil Engineering, Shangqiu Normal University, Shangqiu, 476000, China.
The rational design of microwave absorption (MA) material featuring light weight, wide absorption bandwidth, and infrared stealth property is crucial for military stealth and health protection but remains challenging. Herein, an innovative N-doped carbon nanocage-in-microcage structure with tunable carbon-coated Ni (NC/Ni(HS)) is reported via a reliable Ni-catalyzed and Ni-templated method. The hierarchically hollow structure of nanocage-in-microcage composites can optimize the impedance matching and respond to multiple reflections and scattering of incident microwaves and infrared waves.
View Article and Find Full Text PDFRegen Biomater
October 2024
State Key Laboratory of Refractories and Metallurgy, Key Laboratory of Coal Conversion & New Carbon Materials of Hubei Province, School of Chemistry and Chemical Engineering, Wuhan University of Science and Technology, Wuhan 430081, P.R. China.
Angew Chem Int Ed Engl
November 2024
Institute for Chemical Research, Kyoto University, Uji, Kyoto, 611-0011, Japan.
Opening up [60]fullerene makes itself inherently chiral without loss of congenital π-conjugation. An immoderately large aperture on [60]fullerene, however, renders the molecule less rigid and therefore it would reduce dissymmetry factors. Herein, we examined supramolecular technique in geometrical reinforcement of chiral open-[60]fullerenes by encasing achiral guests such as Ar, CO, and CHCN.
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