Intrinsically flame-retardant polyamide 66 with high flame retardancy and mechanical properties.

The key factor in the synthesis of intrinsic flame retardant polymers is the thermal stability and reactivity of phosphorus-based flame retardants. However, it is difficult to realize both thermal stability and high reactivity by using one phosphorus-based flame retardant. Herein, we proposed a strategy to improve the thermal stability of highly reactive flame-retardant, 4-(2-(((2-carboxyethyl)(phenyl)phosphoryl)oxy)ethoxy)-4-oxohexanoic acid (CPPOA), by reacting it with 1,6-diaminohexane to obtain CPPOA salt, which then was copolymerized with PA66 salt to obtain intrinsic flame-retardant polyamide 66 (FRPA66). The thermal stability of CPPOA was significantly improved. The LOI and vertical combustion grade of FRPA66 with 6 wt% CPPOA reached 27.2% and V-0 rating, respectively. Furthermore, the tensile strength and impact strength of the FRPA66 reached 70 MPa and 5.6 kJ m, respectively. Our work presents an efficient approach to synthesize polymers having high flame retardancy and good mechanical properties, showing high potential for real applications.