Combining a bulky bis(amide) and a reactive one-coordinate TMP (2,2,6,6-tetramethylpiperidide) ligand, a new mixed K/Zn heteroleptic base has been developed for regioselective zincation of fluoroarenes. This special ligand set allows for trapping and structural authentication of the first intermediates of direct Zn-H exchange of fluoroarenes obtained deprotonative metallation, providing mechanistic insights of the processes involved.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9040423 | PMC |
| http://dx.doi.org/10.1039/d2cc00979j | DOI Listing |
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