Anionic stitching polymerization of styryl(vinyl)silanes for the synthesis of sila-cyclic olefin polymers.

Chem Commun (Camb)

Division of Chemistry, Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, Toyonaka, Osaka 560-8531, Japan.

Published: April 2022

AI Article Synopsis

  • Anionic stitching polymerization creates a novel type of polymer made from styryl(vinyl)silanes, featuring fused sila-bicyclic structures in its main chain.* -
  • The resulting polymers exhibit good thermal stability and high glass-transition temperatures, making them suitable for various applications.* -
  • These polymers are also highly transparent in the visible light spectrum, enhancing their potential uses in optics and materials science.*

Article Abstract

Anionic stitching polymerization of styryl(vinyl)silanes has been developed for the synthesis of a new type of silicon- and carbon-containing polymer possessing fused sila-bicyclic structures in the main chain. The obtained polymers were found to be thermally stable with relatively high glass-transition temperatures and highly transparent in the visible light region.

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Source
http://dx.doi.org/10.1039/d2cc00721eDOI Listing

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