The chitosan-modified biochar composite, as a carbohydrate polymer, has received increasing attention and becomes a research hotspot. It is a promising impurity adsorption material, which has potential application value in the agricultural environment fields such as soil improvement and sewage purification. The composite can combine the advantages of biochar with chitosan, and the resulting composite usually exhibits a great improvement in its surface functional groups, adsorption sites, stability, and adsorption properties. In addition, compared to other adsorbents, the composite truly achieves the concept of "waste control by waste". In this paper, the preparation method, composite classification, adsorption mechanism, and models of biochar modified by chitosan are introduced, meanwhile, we also review and summarize their effects on the decontamination of wastewater and soil. In addition to common heavy metal ions, we also review the adsorption and removal of some other organic/inorganic pollutants, including (1) drug residues; (2) dyes; (3) phosphates; (4) radionuclides; (5) perfluorochemicals, etc. Moreover, challenges and prospects for the composite are presented and further studies are called for the chitosan-biochar composite. We believe that the composite will lead to further achievements in the field of environmental remediation.
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http://dx.doi.org/10.1016/j.ijbiomac.2022.04.006 | DOI Listing |
Environ Sci Pollut Res Int
October 2024
School of Resources and Environment, Northeast Agricultural University, Harbin, 150030, PR China.
This study presents the synthesis and evaluation of a magnetic chitosan-modified biochar (M-BC-CS) composite, developed from waste maize straw, for the efficient removal of copper ions (Cu) and methylene blue (MB) dye from aqueous solutions. The composite was characterized using advanced techniques such as SEM, BET, FTIR, XPS, and XRD, confirming its enhanced surface area, porosity, and magnetic properties. The study is aimed at investigating the optimal conditions for adsorption of Cu and MB by M-BC-CS through analysis of the influence of diverse adsorbent dosages, pH levels, reaction times, and initial solution concentrations.
View Article and Find Full Text PDFHuan Jing Ke Xue
September 2024
School of Water and Environment, Chang'an University, Xi'an 710054, China.
To explore the remediation mechanism of chitosan-modified biochar (passivator) on Cd-contaminated farmland soil, pot experiments were conducted to determine the effects of passivator on soil physical and chemical properties, ryegrass biomass, enzyme activity, and the response of soil bacterial diversity and structure. The results showed that when the amount of passivating agent was increased from 0.5% to 3%, the content of available Cd in soil was significantly decreased compared with that in the control, and the above-ground and subsurface biomass of ryegrass was increased by 1.
View Article and Find Full Text PDFBioresour Technol
June 2024
Key Laboratory of Southwestern Chinese Medicine Resources, School of Pharmacy, Chengdu University of Traditional Chinese Medicine, Chengdu 611137, PR China. Electronic address:
In this study, the sorption properties of Cr(VI), As(III), and Pb(II) on chitosan-modified magnetic biochar (CMBC) derived from residues of Ligusticum chuanxiong Hort. were investigated. CMBC was found to be a valuable material for removing three heavy metals from water simultaneously.
View Article and Find Full Text PDFHuan Jing Ke Xue
February 2024
School of Water and Environment, Chang'an University, Xi'an 710054, China.
Chitosan-modified biochar (CBC) was prepared as a low-cost and highly efficient adsorbent for Cd in aqueous solutions. Batch adsorption experiments were conducted to evaluate the adsorption performance. Characterization experiments with SEM-EDS, FTIR, and XPS were used to analyze the surface microstructure and chemical composition of the adsorbent.
View Article and Find Full Text PDFJ Hazard Mater
March 2024
Chongqing Key Laboratory of Agricultural Resources and Environment, College of Resources and Environment, Chongqing 400715, PR China.
Biochar could reshape microbial communities, thereby altering methylmercury (MeHg) concentrations in rice rhizosphere and seeds. However, it remains unclear whether and how biochar amendment perturbs microbe-mediated MeHg production in mercury (Hg) contaminated paddy soil. Here, we used pinecone-derived biochar and its six modified biochars to reveal the disturbance.
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