Crystal structure of 1,1',2,2',4,4'-hexa-iso-propyl-magnesocene.

Acta Crystallogr E Crystallogr Commun

Saarland University, Faculty of Natural Sciences and Technology, Department of Chemistry, Campus Saarbrücken, 66123 Saarbrücken, Germany.

Published: February 2022

The title compound, CpMg or [Mg(CH)], was synthesized from the cor-res-ponding triiso-propyl-cyclo-penta-diene by treatment with -butyl--butyl-magnesium. The structural characterization by single-crystal X-ray diffraction revealed that the compound crystallizes in the triclinic space group with half a mol-ecule per asymmetric unit and a staggered arrangement of the cyclo-penta-dienide ligands.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC8900506PMC
http://dx.doi.org/10.1107/S2056989022001189DOI Listing

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