Exotic quantum phase transitions in metals, such as the electronic nematic state, have been discovered one after another and found to be universal now. The emergence of unconventional density-wave (DW) order in frustrated kagome metal AVSb and its interplay with exotic superconductivity attract increasing attention. We find that the DW in kagome metal is the bond order, because the sizable intersite attraction is caused by the quantum interference among paramagnons. This mechanism is important in kagome metals because the geometrical frustration prohibits the freezing of paramagnons. In addition, we uncover that moderate bond-order fluctuations mediate sizable pairing glue, and this mechanism gives rise to both singlet s-wave and triplet p-wave superconductivity. Furthermore, characteristic pressure-induced phase transitions in CsVCb are naturally understood by the present theory. Thus, both the exotic density wave and the superconductivity in geometrically frustrated kagome metals are explained by the quantum interference mechanism.
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http://dx.doi.org/10.1126/sciadv.abl4108 | DOI Listing |
Nano Lett
January 2025
State Key Laboratory of Structural Analysis for Industrial Equipment & School of Physics, Dalian University of Technology, Dalian 116024 People's Republic of China.
J Phys Chem Lett
January 2025
Institute of Functional Nano & Soft Materials (FUNSOM), Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices, Joint International Research Laboratory of Carbon-Based Functional Materials and Devices, Soochow University, Suzhou 215123, P. R. China.
Alkali element doping has significant physical implications for two-dimensional materials, primarily by tuning the electronic structure and carrier concentration. It can enhance interface electronic interactions, providing opportunities for effective charge transfer at metal-organic interfaces. In this work, we investigated the effects of gradually increasing the level of K doping on the lattice structure and electronic properties of an organometallic coordinated Kagome lattice on a Ag(111) surface.
View Article and Find Full Text PDFInorg Chem
December 2024
Department of Chemistry, Iowa State University, Ames, Iowa 50011, United States.
Investigating material properties is essential to assessing their application potential. While computational methods allow for a fast prediction of the material structure and properties, experimental validation is essential to determining the ultimate material potential. Herein, we report the synthesis and experimental magnetic properties of three previously reported Kagome compounds in the Li-Fe-Ge system.
View Article and Find Full Text PDFEnviron Sci Technol
December 2024
CAS Key Laboratory of Green Process and Engineering, Institute of Process Engineering, Innovation Academy for Green Manufacture, State Key Laboratory of Mesoscience and Engineering, Chinese Academy of Sciences, Beijing 100190, China.
Reducing carbon dioxide (CO) emissions has become increasingly urgent for China, particularly in the industrial sector. Striking a balance between a high CO adsorption capacity and long-term stability under practical conditions is crucial for effectively capturing CO from flue gas. In this study, a series of functionalized MFM-136 adsorbents were synthesized in which -NO and -NH groups were grafted onto the kagome lattice of MFM-136.
View Article and Find Full Text PDFACS Appl Mater Interfaces
December 2024
Beijing Advanced Innovation Center for Materials Genome Engineering, Institute of Solid State Chemistry, University of Science and Technology Beijing, Beijing 100083, China.
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