Initiatives to reduce plastic waste are currently under development worldwide. As a part of it, the European Union and private and public organizations in several countries are designing and implementing regulations for single-use plastics. For example, by 2030, plastic packaging and food containers must be reusable or recyclable. In another approach, researchers are developing biopolymers using biodegradable thermoplastics, such as polyhydroxyalkanoates (PHAs), to replace fossil derivatives. However, their production capacity, high production costs, and poor mechanical properties hinder the usability of these biopolymers. To overcome these limitations, biomaterials reinforced with natural fibers are acquiring more relevance as the world of bioplastics production is increasing. This review presents an overview of PHA-vegetal fiber composites, the effects of the fiber type, and the production method's impact on the mechanical, thermal, barrier properties, and biodegradability, all relevant for biopackaging. To acknowledge the behaviors and trends of the biomaterials reinforcement field, we searched for granted patents focusing on bio-packaging applications and gained insight into current industry developments and contributions.
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http://dx.doi.org/10.3390/polym14061114 | DOI Listing |
Gels
October 2024
Department of Information, Modeling, Electronics and System Engineering (D.I.M.E.S.), University of Calabria, Via P. Bucci, Cubo 39C, I-87036 Rende, Italy.
The recovery of potato waste for circular-economy purposes is a growing area of industrial research. This waste, rich in nutrients and potential for reuse, can be a valuable source of starch for packaging applications. Rheology plays a crucial role in characterizing film-forming solutions before casting.
View Article and Find Full Text PDFInt J Biol Macromol
December 2024
National Center of Excellence for Petroleum, Petrochemicals, and Advance Material, Department of Chemical Engineering, Faculty of Engineering, Kasetsart University, Bangkok 10900, Thailand. Electronic address:
This study developed polyvinyl alcohol (PVA)/carboxymethylcellulose (CMC)-based films, using citric acid (CA) as a non-toxic crosslinking agent, to enhance the shelf life of water-soluble packaging films. Clove essential oil (CEO)-loaded chitosan nanoparticles (CSNPs) were prepared via Pickering emulsion and incorporated into PVA/CMC/CA composite films. The encapsulation of CEO was confirmed by FTIR and optical microscopy.
View Article and Find Full Text PDFHeliyon
September 2024
Department of Mechanical and Aerospace Engineering, Brunel University London, Uxbridge, UB8 3PH, UK.
The increasing global concern over environmental plastic waste has propelled the progress of biodegradable supplies for food packaging. Biopolymer-based packaging is undergoing modifications to enhance its mechanical properties, aligning with the requirements of smart food packaging. Polymer nanocomposites, incorporating reinforcements such as fibers, platelets, and nanoparticles, demonstrate significantly improved mechanical, thermal, optical, and physicochemical characteristics.
View Article and Find Full Text PDFEnzyme Microb Technol
December 2024
CIRIAF, Interuniversity Research Centre on Pollution and Environment "M.Felli", University of Perugia, Via G. Duranti 67, Perugia 06125, Italy.
The extensive utilization of conventional plastics has resulted in a concerning surge in waste. A potential solution lies in biodegradable polymers mostly derived from renewable sources. Cupriavidus necator DSM 545 is a microorganism capable, under stress conditions, of intracellularly accumulating Poly(3-hydroxybutyrate) (PHB), a bio-polyester.
View Article and Find Full Text PDFSci Total Environ
November 2024
Department of Agricultural, Food and Environmental Sciences, Polytechnic University of Marche, Via Brecce Bianche, 60131 Ancona, Italy. Electronic address:
The present study aimed to i) assess the disintegration of a novel bio-packaging during aerobic composting (2 and 6 % tested concentrations) and evaluate the resulting compost ii) analyse the ecotoxicity of bioplastics residues on earthworms; iii) study the microbial communities during composting and in 'earthworms' gut after their exposure to bioplastic residues; iv) correlate gut microbiota with ecotoxicity analyses; v) evaluate the chemico-physical characterisation of bio-packaging after composting and earthworms' exposure. Both tested concentrations showed disintegration of bio-packaging close to 90 % from the first sampling time, and compost chemical analyses identified its maturity and stability at the end of the process. Ecotoxicological assessments were then conducted on Eisenia fetida regarding fertility, growth, genotoxic damage, and impacts on the gut microbiome.
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