Quantum dots (QDs) are usually seen as artificial semiconductor particles exhibiting optical and electronic properties interesting for nanotechnological applications. However, they may also play a role in prebiotic chemistry. Starting from zinc acetate, cadmium acetate, and mercaptosuccinic acid, we demonstrate the formation of ZnCd QDs upon UV irradiation in prebiotic liquid formamide. We show that ZnCd QDs are able to increase the yield of RNA nucleobase synthesis from formamide up to 300 times, suggesting they might have served as universal catalysts in a primordial milieu. Based on the experimentally observed peroxidase-like activity of ZnCd QDs upon irradiation with visible light, we propose that QDs could be relevant to a broad variety of processes relating to the emergence of terrestrial life.
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http://dx.doi.org/10.1089/ast.2021.0099 | DOI Listing |
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May 2024
Suzhou Key Laboratory of Novel Semiconductor-Optoelectronics Materials and Devices, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, Jiangsu, 215123, P. R. China.
A front surface gradient of the absorber valence band can effectively reduce the open-circuit voltage (V) loss of perovskite solar cells by suppressing the minority carrier concentration near the front surface. However, the existing method is limited to the one-step fabrication process, resulting in underachieved photon harvesting and power conversion efficiency (PCE). To solve the problem, ZnCd-based alloy quantum dots (QDs) are utilized to create a valence-band-maximum gradient at the front surface of a two-step processed FAPbI absorber.
View Article and Find Full Text PDFTalanta
April 2023
Department of Chemistry and Biochemistry, Mendel University in Brno, Zemedelska 1, CZ 613 00, Brno, Czech Republic. Electronic address:
Microfluidic paper-based analytical devices modified with molecularly imprinted polymers (μPADs@MIPs) were developed for fluorescent detection of targeted thiols via in situ UV-induced formation of quantum dots (μPADs@MIPs@QDs). The selectivity enhancement by the MIP layer formed on the filter paper surface was demonstrated for the isolation of L-homocysteine from wine. Followed by the addition of metal precursors solution (Zn/Cd/Cu) and UV irradiation, fluorescent quantum dots were formed thus enabling quantitative detection of the thiol (serving as a QD capping agent).
View Article and Find Full Text PDFAstrobiology
May 2022
J. Heyrovsky Institute of Physical Chemistry, Czech Academy of Sciences, Prague, Czech Republic.
Quantum dots (QDs) are usually seen as artificial semiconductor particles exhibiting optical and electronic properties interesting for nanotechnological applications. However, they may also play a role in prebiotic chemistry. Starting from zinc acetate, cadmium acetate, and mercaptosuccinic acid, we demonstrate the formation of ZnCd QDs upon UV irradiation in prebiotic liquid formamide.
View Article and Find Full Text PDFChem Asian J
November 2021
School of Chemistry and Chemical Engineering, Hefei University of Technology, Hefei, Anhui, 230009, P. R. China.
An effective path to synthesize Zn Cd S quantum dots (ZCS QDs) in aqueous phase at room temperature has remained relatively unexplored. Here, we developed a room-temperature, aqueous-phase approach to ZCS QDs, using 3-mercaptopropionic acid (MPA) to adjust the pH of the reaction precursor solution to regulate the competition between sulfur source and hydroxyl group, and realize the large-scale preparation of water-soluble ZCS QDs photocatalyst at room temperature. Without recombination with other materials, and only by regulating the ratio of pH, excess sulfur sources and Zn/Cd, the photocatalytic degradation of rhodamine B (RhB) can reach 98% within 1 min, showing high photocatalytic activity.
View Article and Find Full Text PDFNanomaterials (Basel)
May 2021
School of Materials Science and Engineering, Beijing Institute of Technology, Beijing 100081, China.
The development of visible-light-responsive photocatalysts with high efficiency, stability, and eco-friendly nature is beneficial to the large-scale application of solar hydrogen production. In this work, the production of biosynthetic ternary ZnCdS photocatalysts (Eg = 2.35-2.
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