Revision surgeries several years after the implantation of the prosthesis are unfavorable from the patient's point of view as they expose him to additional discomfort, to risk of complications and are expensive. One of the factors responsible for the aseptic loosening of the prosthesis is the gradual degradation of the cement material as a result of working under considerable loads, in an aggressive environment of the human body. Contaminants present in the surgical field may significantly affect the durability of the bone cement and, consequently, of the entire bone-cement-prosthesis system. The paper presents the results of an analysis of selected mechanical properties of two medium-viscosity bone cements DePuy CMW3 Gentamicin and Heraeus Palamed, for the samples contaminated with saline and blood in the range of 1-10%. The results obtained for compressive strength and modulus of elasticity were subjected to statistical analysis, which estimated the nature of changes in these parameters depending on the amount and type of contamination and their statistical significance.
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http://dx.doi.org/10.3390/ma15062197 | DOI Listing |
JACS Au
December 2024
Sorbonne Université, CNRS, Institut Parisien de Chimie Moléculaire, IPCM, F-75005 Paris, France.
Metallogels built in a bottom-up approach by metal coordination and supramolecular interactions have important potential for the elaboration of smart materials. In this context, we present here the formation of supramolecular coordination polymers driven by the complexation of cobalt(II) or zinc(II) ions with polyoxometalate-based hybrids displaying two terpyridine ligands in a linear arrangement. Thanks to the electrostatic interactions between the polyoxometalate cores and metal nodes, the polymer chains self-assemble into fibers that physically cross-link to form gels above a critical concentration.
View Article and Find Full Text PDFACS Appl Electron Mater
December 2024
CEITEC, Brno University of Technology, Purkyňova 123, 61200 Brno, Czech Republic.
To satisfy the needs of the current technological world that demands high performance and efficiency, a deep understanding of the whole fabrication process of electronic devices based on low-dimensional materials is necessary for rapid prototyping of devices. The fabrication processes of such nanoscale devices often include exposure to an electron beam. A field effect transistor (FET) is a core device in current computation technology, and FET configuration is also commonly used for extraction of electronic properties of low-dimensional materials.
View Article and Find Full Text PDFInt J Nanomedicine
December 2024
Department of Plastic Surgery, Union Hospital, Tongji Medical College, Huazhong University of Science and Technology, Wuhan, 430022, People's Republic of China.
Purpose: Successful regeneration of cranial defects necessitates the use of porous bone fillers to facilitate cell proliferation and nutrient diffusion. Open porous microspheres, characterized by their high specific surface area and osteo-inductive properties, offer an optimal microenvironment for cell ingrowth and efficient ossification, potentially accelerating bone regeneration.
Materials And Methods: An in vitro investigation was conducted to assess the physicochemical properties, porosity, and biocompatibility of PHA-nano-clay open porous microspheres.
ACS Cent Sci
December 2024
Department of Chemical Engineering, Stanford University, Stanford, California 94305, United States.
Stretchable electronics have seen substantial development in skin-like mechanical properties and functionality thanks to the advancements made in intrinsically stretchable polymer electronic materials. Nanoscale phase separation of polymer materials within an elastic matrix to form one-dimensional nanostructures, namely nanoconfinement, effectively reduces conformational disorders that have long impeded charge transport properties of conjugated polymers. Nanoconfinement results in enhanced charge transport and the addition of skin-like properties.
View Article and Find Full Text PDFDent Res J (Isfahan)
November 2024
Department of Orthodontics and Dentofacial Orthopedics, SRM Dental College and Hospital, Chennai, Tamil Nadu, India.
Background: The aim of this study was to compare the mechanical properties of the polymer brackets with metal and ceramic brackets and verify if the polymer brackets could be used clinically.
Materials And Methods: A thorough search was conducted in four electronic databases, including Scopus, PubMed, Cochrane, Ovid, and Lilacs, with article selection based on Preferred Reporting Items for Systematic Reviews and Meta-Analysis standards. A computerized search of the database was done from January 1990 to June 2024.
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