LaCoO perovskites with different spin states of Co were prepared by calcination at 600-1000 °C. LaCoO with electron filling in the e orbital at 1 exhibited a moderate interaction between the surface oxygen, resulting in the best catalytic activity. This was verified by the O p-band center.
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| http://dx.doi.org/10.1039/d2cc00404f | DOI Listing |
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