Starch structure and exchangeable protons contribute to reduced aging of high-amylose wheat bread.

Food Chem

The University of Queensland, Centre for Nutrition and Food Sciences, Queensland Alliance for Agriculture and Food Innovation, Brisbane, QLD 4072, Australia. Electronic address:

Published: August 2022

Breads were prepared from wild-type wheat flour (WTWF) and high-amylose wheat flour (HAWF) with amylose content (AM) 71% and 84%. Melting enthalpy of recrystallized amylopectin (ΔH) increased significantly on storage for wild-type (WT), slightly for 71% AM but not at all for bread with 84% AM. Firmness of bread was positively related to AM content and ΔH. Exchangeable proton populations and mobility in high-amylose wheat bread (HAWB) crumb were higher than WT bread measured by H T NMR, consistent with the higher water content needed to make doughs from HAWF leading to the crumb network being more plasticized and hindering crumb aging. Although starch recrystallization and bread firming increased, no increase in enzyme-resistant starch (RS) content was observed during bread aging, with RS content only dependent on AM content. Although HAWB has a harder crumb than wild-type, it has greater shelf-life stability and higher nutritional value.

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http://dx.doi.org/10.1016/j.foodchem.2022.132673DOI Listing

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Article Synopsis
  • The study explored how high-amylose wheat (HAW) dough behaves rheologically during heating, focusing on the effects of starch properties.
  • At temperatures from 30°C to 90°C, HAW dough showed low torque values due to less starch swelling, and demonstrated good resistance to shear and enzyme degradation at 90°C.
  • The findings suggest that HAW dough’s rheological behaviors mirror their starch pasting profiles, which is important for creating firm-textured, low-viscosity food products.
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