Decarboxylation of Poly[N-(acryloyloxy)phthalimide] as a Versatile Tool for Postpolymerization Modification.

Macromol Rapid Commun

Institute for Chemical Technology and Polymer Chemistry (ITCP), Karlsruhe Institute of Technology (KIT), Engesserstraße 18, 76131, Karlsruhe, Germany.

Published: May 2022

Herein the decarboxylation of poly[N-(acryloyloxy)phthalimide] (PAP) for the synthesis of functionalized polymers is reported. PAP homopolymer and block copolymers are used as precursor polymers for the straightforward functionalization via decarboxylation and subsequent Michael-type addition or nitroxide radical coupling (NRC).

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Source
http://dx.doi.org/10.1002/marc.202200068DOI Listing

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