To clarify the K modified effects over activated carbon (AC) supported Mn-Ce oxide catalysts, several Mn-Ce/AC and K-Mn-Ce/AC mixed oxide catalysts prepared via an impregnation method supported on AC were investigated for low-temperature selective catalytic reduction (SCR) of NO with NH in the simulated sintering flue gas. The Mn-Ce/AC catalyst with a K loading of 8% showed the highest catalytic activity, corresponding to 92.1% NO conversion and 92.5% N selectivity at 225 °C with a space velocity of 12,000 h. Furthermore, the 0.08K-Mn-Ce/AC catalyst exhibited better resistance to SO and HO than Mn-Ce/AC, which could convert 72.3% and 74.1% of NO at the presence of 5% SO and HO, respectively. After K modification, the relative ratios of Mn/Mn as well as Ce/Ce and surface adsorbed oxygen increased. Additionally, the reduction performance of the catalyst was improved obviously, and both acid strength and quantity of acid sites increased significantly after the K species were introduced in Mn-Ce/AC. Especially, the NO adsorption capacity of the catalyst was enhanced, which remarkably promoted the denitration efficiency and SO resistance. The SCR of NO with NH on K-Mn-Ce/AC catalysts followed the L-H mechanism.
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| http://dx.doi.org/10.1021/acsomega.1c07076 | DOI Listing |
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