Using IBM's publicly accessible quantum computers, we have analyzed the entropies of Schrödinger's cat states, which have the form = (1/2) [|0 0 0⋯0〉 + |1 1 1⋯1〉]. We have obtained the average Shannon entropy of the distribution over measurement outcomes from 75 runs of 8192 shots, for each of the numbers of entangled qubits, on each of the quantum computers tested. For the distribution over N fault-free measurements on pure cat states, would approach one as N → ∞, independent of the number of qubits; but we have found that varies nearly linearly with the number of qubits . The slope of the number of qubits differs among computers with the same quantum volumes. We have developed a two-parameter model that reproduces the near-linear dependence of the entropy on the number of qubits, based on the probabilities of observing the output 0 when a qubit is set to |0〉 and 1 when it is set to |1〉. The slope increases as the error rate increases. The slope provides a sensitive measure of the accuracy of a quantum computer, so it serves as a quickly determinable index of performance. We have used tomographic methods with error mitigation as described in the qiskit documentation to find the density matrix and evaluate the von Neumann entropies of the cat states. From the reduced density matrices for individual qubits, we have calculated the entanglement entropies. The reduced density matrices represent mixed states with approximately 50/50 probabilities for states |0〉 and |1〉. The entanglement entropies are very close to one.
Download full-text PDF |
Source |
---|---|
http://dx.doi.org/10.1039/d1cp05255a | DOI Listing |
Nat Commun
January 2025
Beijing National Laboratory for Molecular Sciences (BNLMS), State Key Laboratory of Rare Earth Materials Chemistry and Applications, PKU-HKU Joint Laboratory in Rare Earth Materials and Bioinorganic Chemistry, College of Chemistry and Molecular Engineering, Peking University, Beijing, China.
Dual active sites with synergistic valence state regulation under oxidizing and reducing conditions are essential for catalytic reactions with step-wise mechanisms to modulate the complex adsorption sites of reactant molecules on the surfaces of heterogeneous catalysts with maximized catalytic performances, but it has been rarely explored. In this work, uniformly dispersed CuCo alloy and CoO nanosheet composite catalysts with dual active sites are constructed, which shows huge boost in activity for catalyzing water-gas shift reaction (WGSR), with a record high reaction rate reaching 204.2 μmol g s at 300 °C for CuCoO amongst the reported Cu-based and Co-based catalysts.
View Article and Find Full Text PDFJ Am Chem Soc
January 2025
The Key Laboratory of Synthetic and Biological Colloids, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi 214122, China.
Electrocatalytic nitrate reduction to ammonia (eNRA) is a promising route toward environmental sustainability and clean energy. However, its efficiency is often limited by the slow conversion of intermediates due to spin-forbidden processes. Here, we introduce a novel A-site high-entropy strategy to develop a new perovskite oxide (LaPrNdBaSr)CoO (LPNBSC) for eNRA.
View Article and Find Full Text PDFSci Total Environ
January 2025
Department of Chemistry, Physics, Environmental and Soil Sciences, University of Lleida - AGROTECNIO-CERCA Center, Rovira Roure 191, 25198 Lleida, Spain.
There is limited research on the influence of environmental variables on the interactions of biodegradable microplastics with chromium. This study reports the results of adsorption experiments with Cr and poly(lactic acid) (PLA) in synthetic aqueous solutions. It addresses the influence of the initial oxidation state, Cr(III) or Cr(VI), the effects of UV irradiation and the presence of organic matter.
View Article and Find Full Text PDFGait Posture
January 2025
Department of Neurology, Oregon Health & Science University, Portland, OR, United States. Electronic address:
Background: Gait impairments are common in individuals with mild traumatic brain injury (mTBI), presenting in the acute phase and often persisting in subtle ways over time. Despite the prominence of laboratory gait evaluations, a comprehensive understanding of gait deficits post-mTBI necessitates the examination of various gait domains in real-world environments. Assessing gait during a community ambulation task (CAT) may capture real-world challenges and influence focused interventions or rehabilitation in individuals with mTBI.
View Article and Find Full Text PDFJ Am Chem Soc
January 2025
State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China.
Although microenvironments surrounding single-atom catalysts (SACs) have been widely demonstrated to have a remarkable effect on their catalytic performances, it remains unclear whether the local structure beyond the secondary coordination shells works as well or not. Herein, we employed a series of metal-organic frameworks (MOFs) with well-defined and tunable second-beyond coordination spheres as model SAC electrocatalysts to discuss the influence of long-distance structure on the ammonia synthesis from nitrate, which were synthesized and denoted as Cu-NDI-X (X = NMe, H, F). It is first experimentally confirmed that the remote substitution of function groups beyond the secondary coordination sphere can remarkably affect the activity of ammonia synthesis.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!