Polyacrylic acid--polystyrene-passivated CsPbBr perovskite quantum dots with high photoluminescence quantum yield for light-emitting diodes.

Chem Commun (Camb)

Shanghai Engineering Research Centre of Hierarchical Nanomaterials, School of Chemical Engineering, East China University of Science and Technology, Shanghai 200237, China.

Published: March 2022

We report a novel strategy for the preparation of CsPbBr perovskite quantum dots by polyacrylic acid--polystyrene ligands, which exhibited high stability and photoluminescence quantum yields. The fabricated white light-emitting diodes exhibited luminescence performance with the colour rendering index of 65.5, and a correlated colour temperature of 5464 K.

Download full-text PDF

Source
http://dx.doi.org/10.1039/d2cc00051bDOI Listing

Publication Analysis

Top Keywords

cspbbr perovskite
8
perovskite quantum
8
quantum dots
8
photoluminescence quantum
8
light-emitting diodes
8
polyacrylic acid--polystyrene-passivated
4
acid--polystyrene-passivated cspbbr
4
quantum
4
dots high
4
high photoluminescence
4

Similar Publications

So far, the striking sign reversal in the near-ambient slope of the gap temperature dependence of colloidal CsPbCl perovskite nanocrystals (NCs) compared to its Br counterpart remains unresolved. Pure bromide NCs exhibit a linear gap increase with increasing temperature, to which thermal expansion and electron-phonon interaction equally contribute. In contrast, the temperature slope for the chlorine compound gap is clearly negative.

View Article and Find Full Text PDF

Anti-Scattering Perovskite Scintillator Arrays for High-Resolution Computed Tomography Imaging.

Adv Mater

January 2025

State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun, 130012, P. R. China.

Computed tomography (CT) imaging has emerge as an effective medical diagnostic technique due to its rapid and 3D imaging capabilities, often employing indirect imaging methods through scintillator materials. Arraying scintillators that can confine light scattering to enable high-resolution CT imaging remains an area of ongoing exploration for emerging perovskite scintillators. Here an anti-scattering cesium lead bromide (CsPbBr) scintillator array embedded within a polyurethane acrylate matrix for CT imaging using a cost-effective solution-processed method is reported.

View Article and Find Full Text PDF

Centimeter-Sized CsPbBr Single-Crystal Films for Energy-Resolved Radiation Detection.

ACS Appl Mater Interfaces

January 2025

Beijing Key Laboratory of Construction-Tailorable Advanced Functional Materials and Green Applications Experimental Center of Advanced Materials, School of Materials Science and Engineering, Beijing Institute of Technology, Beijing 100081, China.

Metal halide perovskites (MHPs) are promising materials for radiation detection. Compared with polycrystalline films, single crystals (SCs) have lower defect density, higher carrier mobility, and lifetime. However, the direct synthesis of MHP SCs for large-area flat panel imaging detectors remains challenging.

View Article and Find Full Text PDF

Enhanced Spontaneous Emission Rate and Luminescence Intensity of CsPbBr Quantum Dots Using a High- Microdisk Cavity.

J Phys Chem Lett

January 2025

State Key Laboratory for Mesoscopic Physics and Frontiers Science Center for Nano-optoelectronics, School of Physics, Peking University, Beijing 100871, China.

Perovskite quantum dots (QDs) are high-efficiency optoelectronic materials attracting great interest, but further improvement in the luminescence efficiency is crucial for their application. In this work, we enhance both the spontaneous emission rate and the photoluminescence (PL) intensity of CsPbBr QDs by coupling them to a high quality () factor SiO microdisk cavity. Compared to conventional metal plasmonic cavities, the dielectric cavity structure suppresses the effects of quenching and energy transfer, which could introduce complex fluctuations and nonradiative decays.

View Article and Find Full Text PDF

"Popping the Ion-Basket": Enhancing Thermoelectric Performance of Conjugated Polymers by Blending with Latently Dissociable Perovskite Quantum Dots.

Adv Sci (Weinh)

January 2025

SKKU Advanced Institute of Nanotechnology (SAINT) and Department of Nano Science and Technology, Sungkyunkwan University, Suwon, 16419, Republic of Korea.

A novel additive method to boost the Seebeck coefficient of doped conjugated polymers without a significant loss in electrical conductivity is demonstrated. Perovskite (CsPbBr) quantum dots (QDs) passivated by ligands with long alkyl chains are mixed with a conjugated polymer in a solution phase to form polymer-QD blend films. Solution sequential doping of the blend film with AuCl solution not only doped the conjugated polymer but also decomposed the QDs, resulting in a doped conjugated polymer film embedded with separated ions dissociated from the QDs.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!