Photocatalytic technology has been widely studied by researchers in the field of environmental purification. This technology can not only completely convert organic pollutants into small molecules of CO and HO through redox reactions but also remove metal ions and other inorganic substances from water. This article reviews the research progress of graphene-based photocatalytic nanocomposites in the treatment of wastewater. First, we elucidate the basic principles of photocatalysis, the types of graphene-based nanocomposites, and the role of graphene in photocatalysis (e.g., graphene can accelerate the separation of photon-hole pairs and increase the intensity and range of light absorption). Second, the preparation, characterization, and application of composites in wastewater are introduced. We also discuss the kinetic model of the photocatalytic degradation of pollutants. Finally, the enhancement mechanism of graphene in terms of photocatalysis is not completely clear, and graphene-based photocatalysts with high catalytic efficiency, low cost, and large-scale production have not yet appeared, so there is an urgent need for more extensive and in-depth research.
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http://dx.doi.org/10.1007/s11356-022-19469-4 | DOI Listing |
Environ Sci Pollut Res Int
November 2024
Department of Environmental Health Engineering, School of Public Health, Zanjan University of Medical Sciences, P.O. Box 4515713656, Zanjan, Iran.
In this study, a comprehensive systematic review was conducted to better recognize the applicability of graphene-based photocatalytic processes for the degradation of tetracycline (TC) from water. A broad search strategy was developed for English language articles available in PubMed, Scopus, and Web of Science. The effect of parameters such as pH, TC concentration, photocatalyst dose, radiation source intensity, and the effect of graphene on the process, kinetics, and reuse of the photocatalyst were investigated.
View Article and Find Full Text PDFGels
September 2024
School of Equipment Engineering, Shenyang Ligong University, Shenyang 110159, China.
Converting solar energy into fuels/chemicals through photochemical approaches holds significant promise for addressing global energy demands. Currently, semiconductor photocatalysis combined with redox techniques has been intensively researched in pollutant degradation and secondary energy generation owing to its dual advantages of oxidizability and reducibility; however, challenges remain, particularly with improving conversion efficiency. Since graphene's initial introduction in 2004, three-dimensional (3D) graphene-based photocatalysts have garnered considerable attention due to their exceptional properties, such as their large specific surface area, abundant pore structure, diverse surface chemistry, adjustable band gap, and high electrical conductivity.
View Article and Find Full Text PDFSci Total Environ
December 2024
Department of Civil and Environmental Engineering, Northwestern University, Evanston, IL 60208, USA.
Water Res
September 2024
Department of Civil and Environmental Engineering, Northwestern University, Evanston, IL 60208, USA. Electronic address:
The presence of active pharmaceutical ingredients (APIs) in wastewater effluents and natural aquatic systems threatens ecological and human health. While activated carbon-based adsorbents, such as GAC and PAC, are widely used for API removal, they exhibit certain deficiencies, including reduced performance due to the presence of natural organic macromolecules (NOMs) and high regeneration costs. There is growing demand for a robust, stable, and self-regenerative adsorbent designed for API removal in various environments.
View Article and Find Full Text PDFJ Comput Chem
November 2024
Department of Chemistry, National Institute of Technology, Calicut, India.
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