The research on low-cost, high-performance non platinum group metal (PGM) oxygen reduction reaction (ORR) catalysts is of great significance for the rapid promotion of fuel cells' practical applications. In this work, Mn-N-C catalyst with outstanding activity was prepared through using hydrogel formed by coordination of sodium alginate (SA) and Mnas the precursor. During the preparation process, g-CNwas added to improve the surface area enrich the pore structure of catalysts, as well as to function as the nitrogen source. Compare with commercial Pt/C catalyst, the optimum Mn-N-C catalyst possesses extraordinary ORR activity in alkaline electrolytes, with a half-wave potential () of 0.90 V. In addition, the Mn-N-C catalyst also displays exceptional stability in alkaline and acidic electrolytes, much superior to Pt/C catalyst.
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http://dx.doi.org/10.1088/1361-6528/ac5aed | DOI Listing |
Adv Sci (Weinh)
April 2024
State Key Laboratory of Systems Medicine for Cancer, Renji-Med X Clinical Stem Cell Research Center, Ren Ji Hospital, School of Medicine, Shanghai Jiao Tong University, Shanghai, 200127, China.
Tumor microenvironment (TME)-induced nanocatalytic therapy is a promising strategy for cancer treatment, but the low catalytic efficiency limits its therapeutic efficacy. Single-atom catalysts (SACs) are a new type of nanozyme with incredible catalytic efficiency. Here, a single-atom manganese (Mn)-N/C nanozyme is constructed.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2024
Department of Chemistry, Tsinghua University, Beijing, 100084, China.
The oxygen evolution reaction (OER), characterized by a four-electron transfer kinetic process, represents a significant bottleneck in improving the efficiency of hydrogen production from water electrolysis. Consequently, extensive research efforts have been directed towards identifying single-atom electrocatalysts with exceptional OER performance. Despite the comprehensive understanding of the OER mechanism, its application to other valuable synthetic reactions has been limited.
View Article and Find Full Text PDFChemistry
February 2024
Max Planck Institute for Chemical Energy Conversion, Stiftstrasse 34-36, 45470, Mülheim an der Ruhr, Germany.
Manganese(I) carbonyl complexes bearing a MACHO-type ligand (HN(CH CH PR ) ) readily react in their amido form with CO to generate 4-membered {Mn-N-C-O} metallacycles. The stability of the adducts decreases with the steric demand of the R groups at phosphorous (R=isopropyl>adamantyl). The CO -adducts display generally a lower reactivity as compared to the parent amido complexes.
View Article and Find Full Text PDFACS Catal
November 2023
Giner, Inc, Newton, Massachusetts 02466, United States.
A significant barrier to the commercialization of proton exchange membrane fuel cells (PEMFCs) is the high cost of the platinum-based oxygen reduction reaction (ORR) cathode electrocatalysts. One viable solution is to replace platinum with a platinum-group metal (PGM) free catalyst with comparable activity and durability. However, PGM-free catalyst development is burdened by a lack of understanding of the active site formation mechanism during the requisite high-temperature synthesis step, thus making rational catalyst design challenging.
View Article and Find Full Text PDFAnal Chem
August 2023
Institute of Nanochemistry and Nanobiology School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, P. R. China.
Single-atom catalysts (SACs), a novel kind of electrocatalysts with full metal utilization, have been developed as unique signal amplifiers in several sensing platforms. Herein, based on theoretical prediction of the oxygen reduction reaction (ORR) mechanism on different atom sites, we constructed dual-atomic-site catalysts (DACs), Fe/Mn-N-C, to catalyze luminol-dissolved oxygen electrochemiluminescence (ECL). Computational simulation indicated that the weak adsorption of OH* on a single Fe site was overcome by introducing Mn as the secondary metallic active site, resulting in a synergic dual-site cascade mechanism.
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