High-performance manganese and nitrogen codoped carbon (Mn-N-C) oxygen reduction electrocatalyst from Mncoordinated sodium alginate.

Nanotechnology

CAS Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Provincial Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, People's Republic of China.

Published: March 2022

AI Article Synopsis

  • Researchers are focusing on developing low-cost, efficient catalysts for the oxygen reduction reaction (ORR) to enhance the practical use of fuel cells.
  • The Mn-N-C catalyst was created using a hydrogel from sodium alginate and manganese, with g-CN added to improve its surface area and nitrogen content.
  • This Mn-N-C catalyst shows impressive ORR performance in alkaline environments, outperforming the commercial Pt/C catalyst in both activity and stability.

Article Abstract

The research on low-cost, high-performance non platinum group metal (PGM) oxygen reduction reaction (ORR) catalysts is of great significance for the rapid promotion of fuel cells' practical applications. In this work, Mn-N-C catalyst with outstanding activity was prepared through using hydrogel formed by coordination of sodium alginate (SA) and Mnas the precursor. During the preparation process, g-CNwas added to improve the surface area enrich the pore structure of catalysts, as well as to function as the nitrogen source. Compare with commercial Pt/C catalyst, the optimum Mn-N-C catalyst possesses extraordinary ORR activity in alkaline electrolytes, with a half-wave potential () of 0.90 V. In addition, the Mn-N-C catalyst also displays exceptional stability in alkaline and acidic electrolytes, much superior to Pt/C catalyst.

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Source
http://dx.doi.org/10.1088/1361-6528/ac5aedDOI Listing

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