Treatment of wastewater containing methyl orange dye by fluidized three dimensional electrochemical oxidation process integrated with chemical oxidation and adsorption.

The integrated high-efficiency treatment technology for dye industry wastewater is one of the current research hot topic in industrial wastewater treatment area. This article reports a new fluidized three-dimensional electrochemical treatment process integrating activated carbon adsorption, direct electro-oxidation and ·OH oxidation. In the process, activated carbon is polarized in a fluidized bed electrochemical reactor to enhance the direct electro-oxidation and ·OH oxidation, and there is a synergistic effect of effective adsorption and electrochemical oxidation to strengthen the treatment efficiency. When 200 mg/L methyl orange is processed, its removal rate reaches 99.9% in 30min, and the synergistic efficiency is 57.3%. After 8 cycles of activated carbon reusage in the process, the removal rate of methyl orange still kept at 89.2%. It is also founded that the activated carbon maintains 64.5% of its original adsorption capacity during the cycle. These results shows its interesting application potential in the fields of high-efficiency, low-cost and green treatment of various industrial organic wastewaters. Further improvements should focus on the development of continuous operation model and the improvement of the activated carbon electro-catalytic performance and the practical regeneration ways of the activated carbon particle electrodes.