Compressed Raman methods allow classification between known chemical species with only a few measurements through binary filters. We propose a methodology for binary filter optimization, in which filters are modified at each pixel so that classification can still be achieved pixel by pixel with a few measurements acquired in parallel, while retaining the ability to reconstruct a full spectrum when combining measurements from several pixels. This approach is robust to intensity variations between pixels. It relies on a generalized Bhattacharyya bound and on the Cramér-Rao bound to tailor filters with optimized performance.

Download full-text PDF

Source
http://dx.doi.org/10.1364/OL.447769DOI Listing

Publication Analysis

Top Keywords

compressed raman
8
binary filters
8
raman method
4
method combining
4
combining classification
4
classification estimation
4
estimation spectra
4
spectra optimized
4
optimized binary
4
filters
4

Similar Publications

Pressure-driven phase transformations on MgCa(CO) huntite carbonate.

Phys Chem Chem Phys

January 2025

CELLS-ALBA Synchrotron Light Facility, Cerdanyola del Vallés, 08290, Barcelona, Spain.

Magnesium and calcium carbonate minerals are significant reservoirs of Earth's carbon and understanding their behavior under different conditions is crucial for elucidating the mechanisms of deep carbon storage. Huntite, MgCa(CO), is one of the two stable calcium magnesium carbonate phases, together with dolomite. The distinctive cation coordination environment of Ca atoms compared to calcite-type and dolomite structures makes huntite a comparatively less dense phase.

View Article and Find Full Text PDF

Sodium borohydride dihydrate (NaBH·2HO) forms through dihydrogen bonding between the hydridic hydrogen of the BH ion and the protonic hydrogen of the water molecule. High-pressure structural changes in NaBH·2HO, observed up to 11 GPa through X-ray diffraction and Raman scattering spectroscopy, were analyzed to assess the influence of dihydrogen bonds on its crystal structure. At approximately 4.

View Article and Find Full Text PDF

Controlling vibrational modes and energy gap by creating van der Waals (vdW) heterostructures through strain engineering is a novel approach to tailor the vibrational and electronic properties of two-dimensional (2D) materials. Numerous theoretical and experimental studies have significantly contributed to analysing the properties of transition metal dichalcogenides (TMDs), known for their multifunctional applications. In this study, we investigate the strain and stacking dependent vibrational properties of WSe2/MoSe2 and MoSe2/WSe2/MoSe2 vdW heterostructures using first-principles based density functional theory calculations.

View Article and Find Full Text PDF

Analysis of Residual Stress at the Interface of Epoxy-Resin/Silicon-Wafer Composites During Thermal Aging.

Polymers (Basel)

December 2024

Science and Technology on Reliability Physics and Application of Electronic Component Laboratory, China Electronic Product Reliability and Environmental Testing Research Institute, Guangzhou 511370, China.

During the thermal aging process of epoxy resin, microcracks, interfacial delamination, and warpage are the key factors leading to semiconductor device damage. Here, epoxy-resin specimens (EP-Ss) and epoxy-resin/silicon-wafer composites (EP-SWs) were prepared to analyze the distribution of residual stress (RS) in epoxy resin and its thermal aging process changes. The uniaxial tensile approach and Raman spectroscopy (RAS) showed that the peak shift of aliphatic C-O in EP-Ss was negatively correlated with the external stress, and that the stress correlation coefficient was -2.

View Article and Find Full Text PDF

The development of new urban areas necessitates building on increasingly scarce land, often overlaid on weak soil layers. Furthermore, climate change has exacerbated the extent of global arid lands, making it imperative to find sustainable soil stabilization and erosion mitigation methods. Thus, scientists have strived to find a plant-based biopolymer that favors several agricultural waste sources and provides high strength and durability for sustainable soil stabilization.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!