The present study discusses the ammonia (NH) sensing characteristics, photocatalytic degradation of emerging pollutants, and peroxidase mimic activity of multifunctional multi-walled carbon nanotube-tungsten oxide nanocomposite (MWCNT/WO) prepared by conventional solvothermal method. The prepared MWCNT/WO nanocomposites were characterized by various analytical techniques like XRD, Raman, XPS, N adsorption, FESEM with elemental analysis and diffuse reflection spectroscopy. The prepared 1% MWCNT/WO nanocomposite showed better gas sensing performance for the NH vapors at 10-100 ppm than the pristine WO and the response and recover time of about 13 and 15s towards 20 ppm of ammonia (NH) was achieved. The photocatalytic activity of MWCNT/WO towards organic dyes such as Rhodamine-B (Rh.B) methylene blue (MB) and pharmaceutical compound ciprofloxacin (CIP) were studied and achieved above 90% degradation at 160 min for CIP and 60 min for MB and Rho-B respectively. The radicle scavenging activity for MWCNT/WO nanocomposite showed the predominant formation of hydroxyl (OH) and superoxide radicle (O). Further, the MWCNT/WO nanocomposite showed peroxidase mimic activity and exhibit the limit of detection (LOD) of about 321 nM. From the overall analysis, MWCNT/WO hybrid seems to have potential characteristics that can be explored for multiple functional applications.
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http://dx.doi.org/10.1016/j.chemosphere.2022.134023 | DOI Listing |
ACS Appl Mater Interfaces
January 2025
Department of Chemistry, College of Science, University of Sulaimani, Qliasan St., 46002 Sulaymaniyah, Kurdistan Region, Iraq.
Metal-organic frameworks (MOFs) have emerged as innovative nanozyme mimics, particularly in the area of oxidase catalysis, outperforming traditional MOF-based peroxidase and other nanomaterial-based oxidase systems. This review explores the various advantages that MOFs offer in terms of catalytic activity, low-cost, stability, and structural versatility. With a primary focus on their application in biochemical sensing, MOF-based oxidases have demonstrated remarkable utility, prompting a thorough exploration of their design and modification strategies.
View Article and Find Full Text PDFDalton Trans
January 2025
Key Laboratory of Nonferrous Metal Chemistry and Resources Utilization of Gansu Province and State Key Laboratory of Applied Organic Chemistry, Frontiers Science Center for Rare Isotopes, College of Chemistry and Chemical Engineering, Lanzhou University, 73000 Lanzhou, China.
Mikrochim Acta
January 2025
Department of Pulmonary and Critical Care Medicine, Quzhou People's Hospital, The Quzhou Affiliated Hospital of Wenzhou Medical University, Quzhou, 324000, China.
A smartphone-integrated colorimetric sensor is introduced for the rapid detection of phenolic compounds, including 8-hydroquinone (HQ), p-nitrophenol (NP), and catechol (CC). This sensor relies on the peroxidase-mimicking activity of aspartate-based metal-organic frameworks (MOFs) such as Cu-Asp, Ce-Asp, and Cu/Ce-Asp. These MOFs facilitate the oxidation of a colorless substrate, 3,3',5,5'-tetramethylbenzidine (TMB), by reactive oxygen species (ROS) derived from hydrogen peroxide (HO), resulting in the formation of blue-colored oxidized TMB (ox-TMB).
View Article and Find Full Text PDFBMC Geriatr
December 2024
Department of Internal Medicine, Ankara Training and Research Hospital, Ankara, Turkey.
Unlabelled: BACKGROUND AND RATIONALE: Thyroid dysfunction in older adults often mimics the signs of aging, impacting metabolism and overall physiological balance. While age-related chronic conditions have been extensively studied, the relationship between thyroid function and frailty remains underexplored.
Objective: This study aimed to evaluate the effects of thyroid dysfunction on frailty among individuals aged 65 years and older.
Biosensors (Basel)
December 2024
A.N. Bach Institute of Biochemistry, Research Center of Biotechnology of the Russian Academy of Sciences, Leninsky Prospect 33, 119071 Moscow, Russia.
Gatifloxacin (GAT), an antibiotic belonging to the fluoroquinolone (FQ) class, is a toxicant that may contaminate food products. In this study, a method of ultrasensitive immunochromatographic detection of GAT was developed for the first time. An indirect format of the lateral flow immunoassay (LFIA) was performed.
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