Per- and polyfluoroalkyl substances (PFAS) are increasingly of interest to drinking water utilities due to state regulations, the release of federal and state health advisories, and public concern. Pilot-scale data were fitted for 16 PFAS species and five commercial-activated carbons using an open-source pore and surface diffusion model that includes an automated parameter-fitting tool. The estimated model parameters are presented, and an uncertainty analysis was evaluated considering the expected temporal variability of influent concentrations. Expected treatment performance differed between two seasons in the pilot phase for the same carbon, which was not captured by modeled uncertainty. However, modeling results can support a utility's decision to choose activated carbon, and make design and operational decisions that can address changing water production rates and treatment goals. For the utility that undertook this pilot study and their desired treatment goals, granular activated carbon (GAC) was found to be an effective treatment technology for PFAS removal.
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http://dx.doi.org/10.1061/(asce)ee.1943-7870.0001964 | DOI Listing |
Environ Sci Pollut Res Int
January 2025
The State University of New York College of Environmental Science and Forestry, Syracuse, USA.
Polychlorinated biphenyls (PCBs) are persistent organic pollutants and are emitted during e-waste activities. Once they enter into the environment, PCBs could pose toxic effects to environmental compartments and public health. Reductive dechlorination offers a sustainable solution to manage the PCBs-contaminated environment.
View Article and Find Full Text PDFSci Rep
January 2025
Department of Environmental Engineering, Kwangwoon University, Seoul, 01897, Republic of Korea.
This study explores the enhanced adsorption performance of activated carbon felt (ACF) for Cu(II) and Cd(II) ions, achieved using a dual-synergistic approach combining MnO coating and plasma treatment. ACF's intrinsic properties, including a high surface area (~ 1000-2000 m²/g), large porosity, and excellent mechanical stability, make it a promising material for environmental applications. However, its limited surface functional groups hinder its adsorption efficiency for heavy metals.
View Article and Find Full Text PDFEnviron Res
January 2025
Chemical Process Engineering, P.O. Box 4300, FIN-90014 University of Oulu, Oulu, Finland.
A low-cost and renewable magnetite-pine bark (MPB) sorbent was evaluated in continuous-flow systems for the removal of various pharmaceuticals from municipal wastewater effluent following membrane bioreactor (MBR) treatment. A 33-day small-scale column test (bed volume: 791 cm) was conducted using duplicate columns of biochar (BC, Novocarbo) and activated carbon (AC, ColorSorb) as reference for two columns of BC and MPB in order to compare the efficiency of AC and MPB. After the small-scale column test, the pharmaceutical concentrations were generally below the detection limit.
View Article and Find Full Text PDFEnviron Res
January 2025
Department of Civil and Environmental Engineering, School of Environment and Society, Institute of Science Tokyo, Meguro-ku, Tokyo, 152-8552, Japan.
The treatment of antibiotic wastewater often faces the challenge of simultaneously and effectively degrading multiple components under complex conditions. To address this challenge, magnetite nanoparticles doped ultrafine activated charcoal powder (MNPs/UACP), which effectively catalyzed the decomposition of HO into •OH and HO•, was prepared using chemical co-precipitation. Under optimum conditions (i.
View Article and Find Full Text PDFJ Phys Chem A
January 2025
Departamento de Química, Instituto Tecnológico de Aeronáutica, São José dos Campos, 12228-900 São Paulo, Brazil.
Polycyclic aromatic hydrocarbons (PAHs) exhibit intriguing characteristics that position them as promising candidates for advancements in organic semiconductor technologies. Notably, tetracene finds substantial utility in Electronics due to its application in organic light-emitting diodes (OLEDs) and organic field-effect transistors (OFETs). The strategic introduction of an isoelectronic boron-nitrogen (B,N) pair to replace a carbon-carbon pair in acenes introduces changes in the electronic structure, allowing for the controlled modulation of diradical characteristics.
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