Tuning HAuCl/Sodium Citrate Stoichiometry to Fabricate Chitosan-Au Nanocomposites.

Nanocomposite engineering of biosensors, biomaterials, and flexible electronics demand a highly tunable synthesis of precursor materials to achieve enhanced or desired properties. However, this process remains limited due to the need for proper synthesis-property strategies. Herein, we report on the ability to synthesize chitosan-gold nanocomposite thin films (CS/AuNP) with tunable properties by chemically reducing HAuCl in chitosan solutions and different HAuCl/sodium citrate molar relationships. The structure, electrical, and relaxation properties of nanocomposites have been investigated as a function of HAuCl/sodium citrate molar relation. It was shown that gold particle size, conductivity, Vogel temperature (glass transition), and water content strongly depend upon HAuCl/sodium citrate relationships. Two relaxation processes have been observed in nanocomposites; the -relaxation process, related to a glass transition in wet CS/AuNP films, and the -relaxation related to the local diffusion process of ions in a disordered system. The ability to fine-tune both - and -relaxations may be exploited in the proper design of functional materials for biosensors, biomaterials, and flexible electronics applications.