Ronchi shearing interferometry is a promising technique for in situ wavefront aberration measurement of the projection lens in advanced photolithography systems. The Van Cittert-Zernike theorem has been used to analyze the interference signal of a Ronchi shearing interferometer in the effective interference area (overlapping area of the ±1st diffraction orders produced by the image grating). However, the applicability of this theorem has not been systematically studied. In this work, the analytical expression of the Ronchigram in this area is derived based on the theory of scalar diffraction and incoherent imaging. The results show that only the object and image grating with infinite diffraction orders can fully satisfy the Van Cittert-Zernike theorem. In the finite diffraction orders case, the theorem can be considered approximately applicable in the overlapping area of the ±3rd diffraction orders produced by the image grating. The applicable area extends to the overlapping area of the ±2nd diffraction orders under a shear ratio of less than 1%, which accounts for 97% of the effective interference area. The theoretical analysis has been verified by simulation and fundamental experiments.
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Sci Rep
December 2024
Qatar Environment and Energy Research Institute (QEERI), Hamad Bin Khalifa University (HBKU), Qatar Foundation, Doha, 34110, Qatar.
This study aims to modify raw zeolite with metal oxide nanocomposites to remove nickel (Ni) ions from synthetic wastewater. Novel zeolite-doped magnesium oxide (MgO), iron oxide (FeO), and zinc oxide (ZnO) nanocomposites were synthesized by hydrothermal-calcination methods. The novel zeolite-doped metal oxide nanocomposites were used as adsorbents to remove Ni (II) ions from synthetic wastewater.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
December 2024
Tsinghua University, Department of Chemistry, 1 Qinghuayuan, Haidian District, 100084, Beijing, CHINA.
The in-depth research on the charge transport properties of BN-embedded polycyclic aromatic hydrocarbons (BN-PAHs) still lags far behind studies of their emitting properties. Herein, we report the successfully synthesis of novel ladder-type BN-PAHs (BCNL1 and BCNL2) featuring a highly ordered BC3N2 acene unit, achieved via a nitrogen-directed tandem C-H borylation. Single-crystal X-ray diffraction analysis unambiguously revealed their unique and compact herringbone packing structures.
View Article and Find Full Text PDFLangmuir
December 2024
Department of Chemical Engineering, Hanyang University, Seoul 04763, Korea.
Covalent organic nanotubes offer enhanced stability, robustness, and functionality, compared to their noncovalent counterparts. This study explores constructing polydiacetylene (PDA) nanotubes using a two-step process: self-assembly via noncovalent interactions followed by UV-induced polymerization of a diacetylene template. A promising building block consisting of a hydrogen-bonding headgroup, barbituric acid, linked to a linear diacetylene chain was prepared.
View Article and Find Full Text PDFJ Pharm Sci
December 2024
Jiangsu Key Laboratory of Marine Pharmaceutical Compound Screening, Jiangsu Key Laboratory of Marine Biological Resources and Environment, Co-Innovation Center of Jiangsu Marine Bio-industry Technology, School of Pharmacy, Jiangsu Ocean University, Lianyungang 222005, China. Electronic address:
Polymerase chain reactions (PCR) are most reliable and precise means for nucleic acid analysis of biological samples. A cold-chain system with temperature at around -20°C is generally necessary for storage and transportation of PCR-related reagents. In order to facilitate ambient temperature storage and transportation, this study prepared Taq DNA polymerase and 5 × HS-Taq Mix (as low as 0.
View Article and Find Full Text PDFChem Sci
December 2024
College of Chemistry and Chemical Engineering, Chongqing University Chongqing 401331 China
Oxygen vacancies in Ruddlesden-Popper (RP) perovskites (PV) [AO][ABO] play a pivotal role in engineering functional properties and thus understanding the relationship between oxygen-vacancy distribution and physical properties can open up new strategies for fine manipulation of structure-driven functionalities. However, the structural origin of preferential distribution for oxygen vacancies in RP structures is not well understood, notably in the single-layer ( = 1) RP-structure. Herein, the = 1 RP phase SrNdZnO was rationally designed and structurally characterized by combining three-dimensional (3D) electron diffraction and neutron powder diffraction.
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