Efficient micron-sized droplet separation materials have become a new demand for environmental protection and economic development. However, existing separation methods are difficult to be effectively used for micron-sized water droplets surrounded by viscous oil, and common materials have difficulty maintaining hydrophilicity underoil. Here, inspired by the microstructure of tree xylem, we report a cellulose-polyurethane sponge (CP-Sponge) with wood-like pores and underoil superhydrophilicity using directional freeze-casting. The CP-Sponge has an excellent selective water absorption capacity underoil and compression resilience. This preparation strategy can flexibly control the sponge's dimensional morphology. The designed cylindrical CP-Sponge can be easily installed in the silicone tube of a peristaltic pump. During pump operation, with a simple absorption, compression, and recovery process, the CP-Sponge continuously and effectively removes micron-sized water from crude oil and lubricating oil, reducing residual water in the oil to less than 2 ppm. The absorption-saturated sponge can be dried to continue recycling. Eco-friendly, recyclable, and sustainable artificial porous sponges provide new ideas and inspiration for the practical application of deep dehydration of viscous oils.
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http://dx.doi.org/10.1021/acsami.2c00785 | DOI Listing |
Waste Manag
December 2024
Key Laboratory of Agro-Environment in Downstream of Yangtze Plain/Scientific Observing and Experimental Station of Arable Land Conservation (Jiangsu), Ministry of Agriculture and Rural Affairs, Institute of Agricultural Resources and Environment, Jiangsu Academy of Agricultural Sciences, Nanjing 210014, China. Electronic address:
J Colloid Interface Sci
December 2024
School of Chemical Engineering and ARC Centre of Excellence for Enabling Eco-Efficient Beneficiation of Minerals (UQ Node), The University of Queensland, Brisbane, Queensland 4072, Australia. Electronic address:
Hypothesis: Ion-specific forces in concentrated salt solutions play critical roles in many applications, ranging from biology to engineering, e.g., separating water-soluble minerals in brines by flotation using air bubbles.
View Article and Find Full Text PDFJ Hazard Mater
November 2024
Research Institute for Geo-Resources and Environment, National Institute of Advanced Industrial Science and Technology, Tsukuba, Ibaraki 305-8567, Japan.
Sci Rep
December 2024
School of Aerospace Engineering, Georgia Institute of Technology, Atlanta, GA, 30332, USA.
We report on the proof-of-concept of a low-mass, low-power method for collecting micron-sized sulfuric acid aerosols in bulk from the atmosphere of Venus. The collection method uses four wired meshes in a sandwich structure with a deposition area of 225 cm. It operates in two modes: passive and electrostatic.
View Article and Find Full Text PDFAdv Mater
December 2024
College of Chemistry, State Key Laboratory of Elemento-Organic Chemistry, Frontiers Science Center for New Organic Matter, Nankai University, Tianjin, 300071, P. R. China.
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