AI Article Synopsis

  • Efficient droplet separation materials are increasingly needed for both environmental protection and economic growth, particularly for micron-sized water droplets in viscous oils.
  • Inspired by tree xylem, a new cellulose-polyurethane sponge (CP-Sponge) has been developed using directional freeze-casting, which offers both superhydrophilicity and effective water absorption under oil.
  • The CP-Sponge can be easily integrated into pumps and allows for continuous removal of water from oils, achieving less than 2 ppm residual water, while remaining eco-friendly and recyclable for repeated use.

Article Abstract

Efficient micron-sized droplet separation materials have become a new demand for environmental protection and economic development. However, existing separation methods are difficult to be effectively used for micron-sized water droplets surrounded by viscous oil, and common materials have difficulty maintaining hydrophilicity underoil. Here, inspired by the microstructure of tree xylem, we report a cellulose-polyurethane sponge (CP-Sponge) with wood-like pores and underoil superhydrophilicity using directional freeze-casting. The CP-Sponge has an excellent selective water absorption capacity underoil and compression resilience. This preparation strategy can flexibly control the sponge's dimensional morphology. The designed cylindrical CP-Sponge can be easily installed in the silicone tube of a peristaltic pump. During pump operation, with a simple absorption, compression, and recovery process, the CP-Sponge continuously and effectively removes micron-sized water from crude oil and lubricating oil, reducing residual water in the oil to less than 2 ppm. The absorption-saturated sponge can be dried to continue recycling. Eco-friendly, recyclable, and sustainable artificial porous sponges provide new ideas and inspiration for the practical application of deep dehydration of viscous oils.

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http://dx.doi.org/10.1021/acsami.2c00785DOI Listing

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