Polymer Composites with Cork Particles Functionalized by Surface Polymerization for Fused Deposition Modeling.

Cork powder received as a byproduct from local industries is valorized through the development of composite materials suitable for fused deposition modeling (FDM). For this purpose, a polymeric matrix of acrylonitrile-styrene-butyl acrylate (ASA) is used due to its good mechanical resistance and weather resistance properties. Prior to the manufacturing of the composites, the cork particles are characterized and modified by surface polymerization, creating a layer of poly(butyl acrylate) (PBA). Then, filaments for FDM are prepared by solvent casting and extrusion from ASA and composites with unmodified cork (ASA + C) and PBA-modified cork (ASA + C). PBA is one of the polymers present in the structure of ASA, which increases the compatibility between the cork particles and the polymer matrix. This is evidenced by evaluating the mechanical properties of the composites and examining their fracture surface by scanning electron microscopy. The analysis of the thermal properties shows that the developed composites also present enhanced insulating properties.