Catalytic support effects have been widely studied as a key factor for creating highly active heterogeneous catalysts with limited amounts of rare metal elements. Recently, support effects of metal-organic frameworks (MOFs) started to be investigated using their wide variety in pore size, electronic state, and selective adsorption property. Three types of support effects, namely molecular sieving, charge transfer, and substrate adsorption effects, have been reported on composite catalysts of metal nanoparticles supported on MOFs (M/MOFs). The current reports on heterogeneous catalysis in M/MOFs clearly demonstrated that both catalytic activity and product selectivity can be drastically enhanced and modulated by MOF supports through these support effects, and that application of MOFs as the supports is beneficial for creating novel high performance catalysts with metal nanoparticles. This minireview summarizes the catalytic properties and support effects observed on M/MOFs.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1039/d1nr07659k | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Impact of Copper(II) and Silver(I) Complexes Containing 1,10-Phenanthroline-5,6-dione on Cellular and Virulence Aspects of Scedosporium apiospermum.
Curr Top Med Chem
January 2025
Laboratório de Estudos Avançados de Microrganismos Emergentes e Resistentes (LEAMER), Departamento de Microbiologia Geral, Instituto de Microbiologia Paulo de Góes (IMPG), Universidade Federal do Rio de Janeiro (UFRJ), Rio de Janeiro, Brazil.
Background: Scedosporium apiospermum is a multidrug-resistant filamentous fungus that causes localized and disseminated diseases. Our group has previously described that metalbased complexes containing copper(II) or silver(I) ions complexed with 1,10-phenanthroline-5,6- dione (phendione) inhibited the viability of S. apiospermum conidial cells.
View Article and Find Full Text PDFGuidance for Introducing the Tobacco-Free Generation Policy.
Int J Health Plann Manage
January 2025
SMRI, The University of Sydney, Sydney, Australia.
This article serves as a guide to the Tobacco-Free Generation policy (TFG) for policy-makers, drawing on experiences of negotiations regarding TFG in a wide number of jurisdictions. It explains the underlying concept: the highly addictive nature of nicotine prompts policy focus on preventing initial use by forbidding sales to those born after a prescribed cut-off birthdate, while resisting prohibition for those in older cohorts who may already be nicotine-dependent. The policy signals that there is no safe age for tobacco products.
View Article and Find Full Text PDFEnhancing university students' engagement in studying assistive technology by case-based active learning: a pilot study in Hong Kong.
Disabil Rehabil Assist Technol
January 2025
Department of Biomedical Engineering, The Hong Kong Polytechnic University, Hong Kong SAR, China.
Assistive technology (AT) professionals are in pressing need with nowadays growing aged/disabled population, so as well-designed higher education programs in this field. This study designed and implemented a case-based active learning approach within an undergraduate course related to AT in Hong Kong, and assessed its impact on enhancing student engagement over two academic years. A total of twelve multimedia patient case dossiers on six major physical disabilities were created.
View Article and Find Full Text PDFExamination of Methods to Estimate Productivity Losses in an Economic Evaluation: Using Foodborne Illness as a Case Study.
Pharmacoeconomics
January 2025
Centre for Health Economics Research and Evaluation, University of Technology Sydney, PO Box 123, Broadway, NSW, 2007, Australia.
Background: Cost-utility analyses commonly use two primary methods to value productivity: the human capital approach (HCA) and the friction cost approach (FCA). Another less frequently used method is the willingness-to-pay (WTP) approach, which estimates the monetary value individuals assign to avoiding an illness. In the context of foodborne illnesses (FBI), productivity loss represents one of the most significant economic impacts, particularly in developed nations.
View Article and Find Full Text PDFFostering moral reflectivity in community pharmacists through moral case deliberation using the dilemma method.
Int J Clin Pharm
January 2025
Division of Pharmacoepidemiology and Clinical Pharmacology, Department of Pharmaceutical Sciences, Utrecht University, PO Box 80082, 3508 TB, Utrecht, The Netherlands.
Background: Moral case deliberation has been successfully implemented in multidisciplinary groups of secondary care professionals to support ethical decision making. It has not yet been reported for community pharmacists.
Aim: This study investigated whether moral case deliberation fosters moral reflectivity in community pharmacists.
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!