AI Article Synopsis
- The helical anthracene [4]HA shows changes in fluorescence when subjected to hydrostatic pressure due to a specific photochemical reaction.
- This change in fluorescence is tied to the intramolecular [4+4] photocyclodimerization that occurs as pressure increases.
- By measuring the resulting ratiometric fluorescence, scientists can potentially determine unknown pressures in various solutions.
Article Abstract
One of the helical anthracenes, [4]HA, in which two fused anthracene ends are spatially arranged top and bottom, exhibits a ratiometric fluorescence response due to the hydrostatic pressure-dependent intramolecular [4+4] photocyclodimerization. This ratiometric signalling comes from the formation of an intramolecular stacked species and its subsequent photoreaction upon hydrostatic pressurization. The ratiometric indexes as a function of hydrostatic pressure may enable us to quantify an unknown pressure in solutions.
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| http://dx.doi.org/10.1039/d2cc00428c | DOI Listing |
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