Application of titanium dioxide immobilized on a cellulosic material for the photocatalytic degradation of Acid Black 24 dye in a continuous flow cascade reactor.

Environ Sci Pollut Res Int

Laboratory of Water and Environment, Research team: Analytical Chemistry and Environmental Process Engineering, Department of Chemistry, Faculty of Sciences of El Jadida, University Chouaïb Doukkali, P.O. Box 20, 24000, El Jadida, Morocco.

Published: July 2022

The aim of this work is the study of the photocatalytic degradation of Acid Black 24 dye (AB24), in a continuous flow cascade reactor, using titanium dioxide (TiO) immobilized on a cellulosic material. The results obtained demonstrated a synergistic effect of the two phenomena adsorption and photocatalysis. The effects of various parameters that affect the dye removal efficiency were investigated. The best photocatalytic degradation yield of AB24 molecules is obtained in acidic medium because of the strong attraction between the positively charged catalyst and the anionic dye molecules. The optimum times for obtaining the best yields depend on the initial concentration of the dye, the volume of the treated solution, and the feed rate of the reactor. In addition, reusing the catalytic material several times is technically possible; this can decrease the cost of treatment for a possible industrial scale application.

Download full-text PDF

Source
http://dx.doi.org/10.1007/s11356-022-19210-1DOI Listing

Publication Analysis

Top Keywords

photocatalytic degradation
12
titanium dioxide
8
immobilized cellulosic
8
cellulosic material
8
degradation acid
8
acid black
8
black dye
8
continuous flow
8
flow cascade
8
cascade reactor
8

Similar Publications

Water pollution, resulting from industrial effluents, agricultural runoff, and pharmaceutical residues, poses serious threats to ecosystems and human health, highlighting the need for innovative approaches to effective remediation, particularly for non-biodegradable emerging pollutants. This research work explores the influence of shape-controlled nanocrystalline titanium dioxide (TiO NC), synthesized by a simple hydrothermal method, on the photodegradation efficiency of three different classes of emerging environmental pollutants: phenol, pesticides (methomyl), and drugs (sodium diclofenac). Experiments were conducted to assess the influence of the water matrix on treatment efficiency by using ultrapure water and stormwater (basic) collected from an urban drainage system as matrices.

View Article and Find Full Text PDF

Rhabdophane, CePO∙HO, nanoparticles were prepared by mechanochemical synthesis with different durations and thoroughly characterized by various characterization techniques. X-ray diffraction analysis showed that the optimal synthesis duration was 15 min, since, in this case, pure rhabdophane is obtained, without traces of contamination by the vessel material. The size of the obtained nanoparticles, as determined from high-resolution transmission electron microscopy images, was around 5 nm.

View Article and Find Full Text PDF

Herein, a WO@TCN photocatalyst was successfully synthesized using a self-assembly method, which demonstrated effectiveness in degrading organic dyestuffs and photocatalytic evolution of H. The synergistic effect between WO and TCN, along with the porous structure of TCN, facilitated the formation of a heterojunction that promoted the absorption of visible light, accelerated the interfacial charge transfer, and inhibited the recombination of photogenerated electron-hole pairs. This led to excellent photocatalytic performance of 3%WO@TCN in degrading TC and catalyzing H evolution from water splitting under visible-light irradiation.

View Article and Find Full Text PDF

A covalent organic framework (COF) has emerged as a promising photocatalyst for the removal of pharmaceutical and personal care product (PPCP) contaminants; however, high-performance COF photocatalysts are still scarce. In this study, three COF photocatalysts were successfully synthesized by the condensation of benzo[1,2-b:3,4-b':5,6-b'']trithiophene-2,5,8-tricarbaldehyde (BTT) with 4,4',4''-(1,3,5-triazine-2,4,6-triyl)trianiline (TAPT), 1,3,5-Tris(4-aminophenyl)benzene (TAPB), and 4,4',4''-nitrilotris(benzenamine) (TAPA), namely, BTT-TAPA, BTT-TAPB, and BTT-TAPT, respectively. The surface areas of BTT-TAPA, BTT-TAPB, and BTT-TAPT were found to be 800.

View Article and Find Full Text PDF

Resveratrol-Based Carbamates as Selective Butyrylcholinesterase Inhibitors: Design, Synthesis, Computational Study and Biometal Complexation Capability.

Molecules

January 2025

Department of Organic Chemistry, Faculty of Chemical Engineering and Technology, University of Zagreb, Trg Marka Marulića 19, HR-10 000 Zagreb, Croatia.

Considering our previous experience in the design of new cholinesterase inhibitors, especially resveratrol analogs, in this research, the basic stilbene skeleton was used as a structural unit for new carbamates designed as potentially highly selective butyrylcholinesterase (BChE) inhibitors with excellent absorption, distribution, metabolism, excretion and toxicity ADMET properties. The inhibitory activity of newly prepared carbamates - was tested toward the enzymes acetylcholinesterase (AChE) and BChE. In the tested group of compounds, the leading inhibitors were and , which achieved excellent selective inhibitory activity for BChE with IC values of 0.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!