Cyclic and acyclic vinyl substituted β-keto/enol carbonyl substrates, on reaction with arynes, result in differentially substituted naphthyl carbocycles, hitherto difficult to synthesize with existing protocols. While the substitutions on the arynes have no role, the ring size of the cyclic β-keto/enol esters has a profound influence on the product formation.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1039/d1cc06810e | DOI Listing |
Publication Analysis
Top Keywords
cascade aryne
4
aryne insertion/vinylogous
4
insertion/vinylogous aldol
4
aldol reaction
4
reaction vinyl-substituted
4
vinyl-substituted β-keto/enol
4
β-keto/enol carbonyls
4
carbonyls cyclic
4
cyclic acyclic
4
acyclic vinyl
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!