Pyrolysis temperature and feedstock affected Cr(VI) removal capacity of sulfidated zerovalent iron: Importance of surface area and electrical conductivity.

Herein, feedstock (pinewood, rice straw, and dairy manure) and pyrolysis temperature (300, 500, and 700 °C) were selected as the influencing factors of properties of biochar (BC) to identify the contribution of biochar's matrix on Cr(VI) removal by BC-supported sulfidated zero-valent iron (S-ZVI/BC). Results showed that higher temperature was more conducible to improve the electrochemical properties and specific surface areas of composites. Raman spectra of S-ZVI supported by pinewood-derived BC (S-ZVI/PBC) showed the I/I ratio increased from 0.639 to 0.975 for the composites prepared at 300-700 °C, indicating the increased structural defects and resulting in the greatest Cr(VI) removal (35.81 mg g) and reduction (30.21 mg g) amounts of S-ZVI/PBC700. Besides, S-ZVI/PBC exhibited greater electrochemical reactivity and surface area than S-ZVI harbored by BC from dairy manure and rice straw. Additionally, Pearson correlation analysis revealed that Cr(VI) removal was significantly positively correlated to surface area (R = 0.90) and negatively correlated to Tafel corrosive potential (R = 0.88). Both desorption experiment and XPS spectra of spent sorbents showed that reduction predominated the detoxifying mechanism of Cr(VI) followed by adsorption (due to corrosively-generated iron oxides and BC) and precipitation (CrS). This suggested that biochar with greater specific surface area and electrical conductivity is more favorable to immobilize S-ZVI with respect to Cr(VI) removal.