The chapter draws a line connecting some recent results where the role of ions is found essential in sealing more or less pre-organized assemblies of macromolecules. We draw some dots along the line that starts from the effect of the ionic atmosphere and ends with the chemical bonds formed by multivalent ions acting as bridges between macromolecules. Many of these dots involve structurally disordered peptides and disordered regions of proteins. A broad perspective of the role of multivalent ions in assisting the assembly process, shifting population in polymorphic states, and sealing protein aggregates, is suggested.
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http://dx.doi.org/10.1007/978-1-0716-1546-1_14 | DOI Listing |
J Am Chem Soc
December 2024
Adaptive Supramolecular Nanosystems Group, University of Montpellier, Institut Européen des Membranes, ENSCM-CNRS, UMR5635, Place E. Bataillon CC047, Montpellier 34095, France.
Aquaporins (AQPs) are natural proteins that can selectively transport water across cell membranes. Heterogeneous H-bonding of water with the inner wall of the pores of AQPs is of maximal importance regarding the optimal stabilization of water clusters within channels, leading to selective pore flow water transport against ions. To gain deeper insight into the water permeation mechanisms, simpler artificial water channels (AWCs) have been developed.
View Article and Find Full Text PDFEnviron Sci Technol
December 2024
School of Civil & Environmental Engineering, Georgia Institute of Technology, Atlanta, Georgia 30332, United States.
Nanofiltration technology holds significant potential for precisely separating monovalent and multivalent ions, such as lithium (Li) and magnesium (Mg) ions, during lithium extraction from salt lakes. This study bridges a crucial gap in understanding the impact of the membrane spatial charge distribution on ion-selective separation. We developed two types of mixed-charge membranes with similar pore sizes but distinct longitudinal and horizontal distributions of oppositely charged domains.
View Article and Find Full Text PDFJ Colloid Interface Sci
December 2024
College of Materials Science and Engineering, Qingdao University, Qingdao, Shandong 266000, China. Electronic address:
In the realm of energy storage, flexible portable supercapacitors have been receiving increasing attention in the last few years. Nonetheless, the process of choosing appropriate flexible materials remains challenging. Herein, we successfully synthesized a flower-like MnCoO@FeCoNi-LDH/CC (MnCo@FCN/CC) hierarchically nanostructured electrode material by anchoring MnCoO (MnCo) on a flexible carbon cloth (CC) substrate first and then loading FeCoNi-LDH nanosheets on MnCoO.
View Article and Find Full Text PDFPhys Chem Chem Phys
December 2024
College of Physics and Energy, Fujian Normal University, Fujian Provincial Solar Energy Conversion and Energy Storage Engineering Technology Research Center, Fuzhou 350117, China.
Finding suitable anode materials for multivalent ion batteries (MuIBs) is the key to improving theoretical capacity, reducing development costs and enhancing the safety of energy storage batteries. In recent years, monolayer GeTe has been reported as an anode material in monovalent ion batteries, but it has not received much attention in MuIBs. This article uses first principles methods based on density functional theory (DFT) to explore the application prospects of monolayer GeTe with a unique serrated wrinkled layer structure as an anode material for multivalent metal ion (Al/Mg/Ca) batteries.
View Article and Find Full Text PDFEnviron Sci Pollut Res Int
December 2024
Department of Chemical Engineering and Analytical Chemistry, Faculty of Chemistry, University of Barcelona, 08028, Barcelona, Spain.
In this paper, copper oxide supported manganese oxide octahedral molecular sieves (CuO-OMS-2) composite was successfully synthesized and subsequently investigated for the degradation and mineralization of phenol via peroxymonosulfate (PMS) activation. It was confirmed that the incorporation of CuO significantly promoted multivalent metals transition and oxygen vacancies generation. At initial pH 5.
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