Bifunctional Single-Atom Cobalt Electrocatalysts with Dense Active Sites Prepared via a Silica Xerogel Strategy for Rechargeable Zinc-Air Batteries.

The N-doped cobalt-based (Co) bifunctional single atom catalyst (SAC) has emerged as one of the most promising candidates to substitute noble metal-based catalysts for highly efficient bifunctionality. Herein, a facile silica xerogel strategy is elaborately designed to synthesize uniformly dispersed and dense Co-N active sites on N-doped highly porous carbon networks (Co-N-C SAC) using economic biomass materials. This strategy promotes the generation of massive mesopores and micropores for substantially improving the formation of Co-N moieties and unique network architecture. The Co-N-C SAC electrocatalysts exhibit an excellent bifunctional activity with a potential gap (ΔE) of 0.81 V in alkaline medias, outperforming those of the most highly active bifunctional electrocatalysts. On top of that, Co-N-C SAC also possesses outstanding performance in ZABs with superior power density/specific capacity. This proposed synthetic method will provide a new inspiration for fabricating various high-content SACs for varied applications.