A flexible functionalized cyclotriphosphazene hexacarboxylic acid, hexakis(4-carboxylatephenoxy) cyclotriphosphazene (HCPCP), is used for the synthesis of a family of fluorescent Ln-HCPCP frameworks (Ln = La, Pr, Nd, Gd, and Ho). Structural analysis shows that the compounds exhibit 3D structures with [Ln(COO)], secondary building units formed by Ln-O-C-O-Ln connection. Then the molecules are connected to each other through HCPCP, forming rectangular channels along the -direction. Interestingly, the fluorescence sensing studies show that compound could be used as a multifunctional fluorescence sensor toward volatile organic compounds via different fluorescence emission behaviors. Moreover, a series of Dye@La-HCPCP composites (Dye = rhodamine B, safranine T, crystal violet, and malachite green) are successfully prepared with different quantum yields by the solvothermal reaction followed by cation exchanges.

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http://dx.doi.org/10.1021/acs.inorgchem.1c03405DOI Listing

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