Novel Temperature-Responsive Rosin-Derived Supramolecular Hydrogels Constructed by New Semicircular Aggregates.

A highly water-soluble rosin-based surfactant (C-MPA-Na) was synthesized. Novel temperature-responsive supramolecular hydrogels were further prepared using C-MPA-Na. The microstructure and the mechanical properties of the hydrogels were investigated. Unexpectedly, instead of the long one-dimensional structure, a new kind of twisted semicircular aggregate was formed in the hydrogels, which was rarely reported. Besides, the hydrogels possessed excellent shear-recovery properties. Upon heating to 40 °C, the hydrogels transformed into viscoelastic solutions, which were constructed by worm-like micelles. By adjusting the temperature, the hydrogels and the viscoelastic solutions could be freely transformed. Nuclear magnetic resonance spectroscopy and Fourier transform infrared spectroscopy were used to further explore the possible self-assembly mechanism of C-MPA-Na. The curved alkane chain which partially overlapped with rosin's rigid skeleton became stretched when heated to 40 °C. The introduction of the rosin rigid skeleton endowed the supramolecular hydrogels with a novel microstructure and contributed to the development of strategies for the utilization of forest resources.