A reaction of trisodium phosphide (NaP) with chlorosilanes allows for simple derivatization into silyl- and cyano-substituted phosphanide species which were compared with each other. The recently discovered cyano(triphenylsilyl)phosphanide shows unique coordination properties compared to bis(silyl)phosphides.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1039/d1dt04223h | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Simple conversion of trisodium phosphide, NaP, into silyl- and cyanophosphides and the structure of a terminal silver phosphide.
Dalton Trans
March 2022
Department of Chemistry and Applied Biosciences ETH Zurich, Vladimir-Prelog-Weg 1, CH-8049 Zurich, Switzerland.
A reaction of trisodium phosphide (NaP) with chlorosilanes allows for simple derivatization into silyl- and cyano-substituted phosphanide species which were compared with each other. The recently discovered cyano(triphenylsilyl)phosphanide shows unique coordination properties compared to bis(silyl)phosphides.
View Article and Find Full Text PDFElectrochemical Na-Insertion/Extraction Property of Ni-Coated Black Phosphorus Prepared by an Electroless Deposition Method.
ACS Omega
August 2017
Department of Materials Chemistry, Faculty of Engineering, and Institute of Carbon Science and Technology, Faculty of Engineering, Shinshu University, 4-17-1 Wakasato, Nagano 380-8553, Japan.
Electrical conductivity is one of the properties required for an active material, and it is extremely essential to exert its potential. In the present study, the strategy of coating a metal at a single particle level by an electroless deposition method was applied to enhance the cycling performance of phosphorus-based negative electrodes for Na-ion batteries. The deposition morphology and composition of the Ni coating layer were characterized by field-emission scanning electron microscopy, scanning transmission electron microscopy, and X-ray diffraction.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!